Quantum mechanics

406 quotes found

"I have observed in teaching quantum mechanics, and also in learning it, that students go through an experience similar to the one that Pupin describes. The student begins by learning the tricks of the trade. He learns how to make calculations in quantum mechanics and get the right answers, how to calculate the scattering of neutrons by protons and so forth. To learn the mathematics of the subject and to learn how to use it takes about six months. This is the first stage in learning quantum mechanics, and it is comparatively painless. The second stage comes when the student begins to worry because he does not understand what he has been doing. He worries because he has no clear physical picture in his head. He gets confused in trying to arrive at a physical explanation for each of the mathematical tricks he has been taught. He works very hard and gets discouraged because he does not seem to be able to think clearly. This second stage often lasts six months or longer. It is strenuous and unpleasant. Then, unexpectedly, the third stage begins. The student suddenly says to himself, “I understand quantum mechanics,” or rather he says, “I understand now that there isn’t anything to be understood.” The difficulties which seemed so formidable have mysteriously vanished. What has happened is that he has learned to think directly and unconsciously in quantum-mechanical language. He is no longer trying to explain everything in terms of prequantum conceptions. The duration and severity of the second stage are decreasing as the years go by. Each new generation of students learns quantum mechanics more easily than their teachers learned it. The students are growing more detached from prequantum pictures. There is less resistance to be broken down before they feel at home with quantum ideas. Ultimately, the second stage will disappear entirely. Quantum mechanics will be accepted by students from the beginning as a simple and natural way of thinking, because we shall all have grown used to it. By that time, if science progresses as we hope, we shall be ready for the next big jump into the unknown."

- Quantum mechanics

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"In this connection the "classical object" is usually called apparatus, and its interaction with the electron is spoken of as measurement. However, it must be emphasized that we are here not discussing a process of measurement in which the physicist-observer takes part. By measurement, in quantum mechanics, we understand any process of interaction between classical and quantum objects, occurring apart from and independently of any observer. The importance of the concept of measurement in quantum mechanics was elucidated by N. Bohr. We have defined "apparatus" as a physical object which is governed, with sufficient accuracy, by classical mechanics. Such, for instance, is a body of large enough mass. However, it must not be supposed that apparatus is necessarily macroscopic. Under certain conditions, the part of apparatus may also be taken by an object which is microscopic, since the idea of "with sufficient accuracy" depends on the actual problem proposed. Thus, the motion of an electron in a Wilson chamber is observed by means of the cloudy track which it leaves, and the thickness of this is large compared with atomic dimensions; when the path is determined with such low accuracy, the electron is an entirely classical object. Thus quantum mechanics occupies a very unusual place among physical theories: it contains classical mechanics as a limiting case, yet at the same time it requires this limiting case for its own formulation."

- Quantum mechanics

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"I argue that what breathes fire into the QM equations is field-theoretic what-it's-likeness: "microqualia" to use a philosopher's term of art. The different values of the solutions to the ultimate physical equations exhaustively yield the abundance of different values of subjectivity. There is no room for dualism; "nomological danglers"; causally inert epiphenomena; classical, porridge-like lumps of otherwise insentient but magically mind-secreting matter, etc. There is no "explanatory gap" because there aren't any material objects - not even brains or nerve cells as commonly (mis)perceived. Instead, over millions of years, non-equilibrium thermodynamics and universal, (neo-)Darwinian principles of natural selection have contrived to organise a minimal and self-intimating subjective sludge of microqualia into complex functional living units. Initially, these units have taken the form of self-replicating, information-bearing biomolecular patterns. Eventually, selection-pressure has given rise to complex minds as well, albeit as just one part of the throwaway host vehicles by which our genes leave copies of themselves. Conscious mind, on this proposal, is a triumph of organisation: our egocentric virtual worlds are warm and gappy QM-coherent states of consciousness. Contra materialist metaphysics, sentience of any kind is not the daily re-enactment of an ontological miracle. Moreover the idea that what-it's-like-ness is the fire in the equations is (at least) consistent with orthodox relativistic quantum field theory - because the theorists' key notions (e.g. that of a field, string, brane, etc) are defined purely mathematically. In other cases, they readily lend themselves to such a reconstruction. Using the word "physical" doesn't add anything of substance."

- Quantum mechanics

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"It is truly surprising how little difference all this makes. Most physicists use quantum mechanics every day in their working lives without needing to worry about the fundamental problem of its interpretation. Being sensible people with very little time to follow up all the ideas and data in their own specialties and not having to worry about this fundamental problem, they do not worry about it. A year or so ago, while Philip Candelas (of the physics department at Texas) and I were waiting for an elevator, our conversation turned to a young theorist who had been quite promising as a graduate student and who had then dropped out of sight. I asked Phil what had interfered with the ex-student’s research. Phil shook his head sadly and said, “He tried to understand quantum mechanics.” So irrelevant is the philosophy of quantum mechanics to its use, that one begins to suspect that all the deep questions about the meaning of measurement are really empty, forced on us by our language, a language that evolved in a world governed very nearly by classical physics. But I admit to some discomfort in working all my life in a theoretical framework that no one fully understands. And we really do need to understand quantum mechanics better in quantum cosmology, the application of quantum mechanics to the whole universe, where no outside observer is even imaginable. The universe is much too large now for quantum mechanics to make much difference, but according to the big-bang theory there was a time in the past when the particles were so close together that quantum effects must have been important. No one today knows even the rules for applying quantum mechanics in this context."

- Quantum mechanics

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"The experimental verification of violations of Bell’s inequality for randomly set measurements at space-like separation is the most astonishing result in the history of physics. Theoretical physics has yet to come to terms with what these results mean for our fundamental account of the world. Experimentalists, from Freedman and Clauser and Aspect forward, deserve their share of the credit for producing the necessary experimental conditions and for steadily closing the experimental loopholes available to the persistent skeptic. But the great achievement was Bell’s. It was he who understood the profound significance of these phenomena, the prediction of which can be derived easily even by a freshman physics student. Unfortunately, many physicists have not properly appreciated what Bell proved: they take the target of his theorem— what the theorem rules out as impossible—to be much narrower and more parochial than it is. Early on, Bell’s result was often reported as ruling out determinism, or hidden variables. Nowadays, it is sometimes reported as ruling out, or at least calling in question, realism. But these are all mistakes. What Bell’s theorem, together with the experimental results, proves to be impossible (subject to a few caveats we will attend to) is not determinism or hidden variables or realism but locality, in a perfectly clear sense. What Bell proved, and what theoretical physics has not yet properly absorbed, is that the physical world itself is non-local."

- Bell's theorem

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"If Monod and Weinberg are truly speaking for the twentieth century, then I prefer the eighteenth. But in fact Monod and Weinberg, both of them first-rate scientists and leaders of research in their specialties, are expressing a point of view which does not take into account the subtleties and ambiguities of twentieth-century physics. The roots of their philosophical attitudes lie in the nineteenth century, not in the twentieth. The taboo against mixing knowledge with values arose during the nineteenth century out of the great battle between the evolutionary biologists led by Thomas Huxley and the churchmen led by Bishop Wilberforce. Huxley won the battle, but a hundred years later Monod and Weinberg were still fighting the ghost of Bishop Wilberforce.… For the biologists, every step down in size was a step toward increasingly simple and mechanical behavior. A bacterium is more mechanical than a frog, and a DNA molecule is more mechanical than a bacterium. But twentieth-century physics has shown that further reductions in size have an opposite effect. If we divide a DNA molecule into its component atoms, the atoms behave less mechanically than the molecule... ... If we divide an atom into nucleus and electrons, the electrons are less mechanical than the atom. There is a famous experiment, originally suggested by Einstein, Podolsky and Rosen in 1935 as a thought experiment to illustrate the difficulties of quantum theory, which demonstrates that the notion of an electron existing in an objective state independent of the experimenter is untenable. The experiment has been done in various ways with various kinds of particles, and the results show clearly that the state of a particle has a meaning only when a precise procedure for observing the state is prescribed. Among physicists there are many different philosophical viewpoints, and many different ways of interpreting the role of the observer in the description of subatomic processes. But all physicists agree with the experimental facts which make it hopeless to look for a description independent of the mode of observation. When we are dealing with things as small as atoms and electrons, the observer or experimenter cannot be excluded from the description of nature. In this domain, Monod's dogma, "The cornerstone of the scientific method is the postulate that nature is objective," turns out to be untrue. … We are saying only that if as physicists we try to observe in the finest detail the behavior of a single molecule, the meaning of the words "chance" and "mechanical" will depend upon the way we make our observations. The laws of subatomic physics cannot even be formulated without some reference to the observer. "Chance" cannot be defined except as a measure of the observer's ignorance of the future. The laws leave a place for mind in the description of every molecule."

- EPR paradox

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"Relativity principles require us to associate mass with the energy of radiation, and it is reasonable to suppose... an exchange of ... [T]he exchange of momentum between free electrons and radiation is very similar to the exchange... when two particles collide. ...[A] beam of light should be considered as an assembly of "units", each or which [using light (\nu), (h), speed of light (c)] possesses energy (W), momentum (p), and mass (m), given byW = h\nu; \; p = \frac{h\nu}{c}; \; m = \frac{h\nu}{c^2}. \quad 17(14)...This general picture was first suggested by Einstein... The units are now called photons... [T]he spreading of light by diffraction cannot be permanently concentrated in a small volume like the energy of a material particle. ...The pressure p, exerted by a parallel beam incident normally on a body which completely absorbs it, is...p = \rho_p, \quad ...17(15) where \rho_p is the energy per unit volume of the incident radiation. ...[C]onsider the radiation pressure of a parallel beam of light, incident on an absorbing body... the light is of frequency \nu and... there are N quanta per unit volume. Then...\rho_p = Nh\nu. \quad ...17(18)[A]ll the quanta in a cylinder of volume c [speed of light multiplied by unit area] cubic centimetres are incident upon unit area of the surface in one second, the pressure...p = NcP, \quad ...17(19)where P is the momentum of one photon. Combining...P = \frac{h\nu}{c} = \frac{h}{\lambda}.[Experimental] results... for isotropic radiation are in agreement..."

- Uncertainty principle

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"Suppose... motion of an electron in the absence of a field of force, is to be investigated... by testing the validity of [no force implies zero acceleration]...\frac{d^2q}{dt^2} = 0, \quad ...18(3)...q ...the position of the particle at time t. The... procedure is to measure the position and momentum of the electron at... time t = t_0... to obtain two "initial conditions" which can be inserted in the solution of 18(3)... then calculate the position and momentum at some later time... and see if the calculation agrees with... observation... Suppose we observe... with light of wavelength \lambda. ...[D]iffraction of the wave sets the limit to the accuracy of a position measurement...\vartriangle q \sim \frac{\lambda}{2sin\theta}, \quad ...18(4)where \vartriangle q is the probable error in... q, and \theta is the semi-angle of the cone of rays accepted by the microscope... [and] \sim means "at least of the order of magnitude of". The experiment of Compton... shows that the interaction... involves an exchange of momentum. We may assume that the momenta... were exactly known before their interaction, but... [those] after the interaction depends on the accuracy [of the] momentum exchanged during the interaction. [T]he photon enters the microscope, and... we know its direction... within an angle 2\theta. Any attempt [to reduce] the effective aperture... increases \vartriangle q. Thus... the momentum of the photon in the plane [in which q is measured] perpendicular to the axis of the microscope... is uncertain by an amount\vartriangle p \sim \frac{2h\nu}{c}sin\theta \quad. ...18(5)The momentum of the particle after the interaction is uncertain by \vartriangle p. Combining... we have\vartriangle p \vartriangle q \sim \frac{\lambda}{2sin\theta} \frac{2h\nu}{c} sin\theta,i.e.,\vartriangle p \vartriangle q \sim h \quad. ...18(6)"

- Uncertainty principle

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"In contemplating the papers Einstein wrote in 1905, I often find myself wondering which of them is the most beautiful. It is a little like asking which of Beethoven’s symphonies is the most beautiful. My favorite, after years of studying them, is Einstein’s paper on the blackbody radiation. [...] Part of being a great scientist is to know—have an instinct for—the questions not to ask. Einstein did not try to derive the Wien law. He simply accepted it as an empirical fact and asked what it meant. By a virtuoso bit of reasoning involving statistical mechanics (of which he was a master, having independently invented the subject over a three-year period beginning in 1902), he was able to show that the statistical mechanics of the radiation in the cavity was mathematically the same as that of a dilute gas of particles. As far as Einstein was concerned, this meant that this radiation was a dilute gas of particles—light quanta. But, and this was also characteristic, he took the argument a step further. He realized that if the energetic light quanta were to bombard, say, a metal surface, they would give up their energies in lump sums and thereby liberate electrons from the surface in a predictable way, something that is called the photoelectric effect. [...] In the first place, not many physicists were even interested in the subject of blackbody radiation for at least another decade. Kuhn has done a study that shows that until 1914 less than twenty authors a year published papers on the subject; in most years there were less than ten. Planck, who was interested, decided that Einstein’s paper was simply wrong."

- Photoelectric effect

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"Quantum computational approaches improve upon classical methods for a number of specialized tasks. The extent of quantum computing’s applicability is still being determined. It does not provide efficient solutions to all problems; neither does it provide a universal way of circumventing the slowing of Moore’s law. Strong limitations on the power of quantum computation are known; for many problems, it has been proven that quantum computation provides no significant advantage over classical computation. Grover’s algorithm, the other major algorithm of the mid- 1990s, provides a small speedup for unstructured search algorithms. But it is also known that this small speedup is the most that quantum algorithms can attain. Grover’s search algorithm applies to unstructured search. For other search problems, such as searching an ordered list, quantum computation provides no significant advantage over classical computation. Simulation of quantum systems is the other significant application of quantum computation known in the mid-1990s. Of interest in its own right, the simulation of increasingly larger quantum systems may provide a bootstrap that will ultimately lead to the building of a scalable quantum computer. After Grover’s algorithm, there was a hiatus of more than five years before a significantly new algorithm was discovered. During that time, other areas of quantum information processing, such as quantum error correction, advanced significantly. In the early 2000s, several new algorithms were discovered. Like Shor’s algorithm, these algorithms solve specific problems with narrow, if important, applications. Novel approaches to constructing quantum algorithms also developed. Investigations of quantum simulation from a quantum-information-processing point of view have led to improved classical techniques for simulating quantum systems, as well as novel quantum approaches. Similarly, the quantum-information-processing point of view has led to novel insights into classical computing, including new classical algorithms. Furthermore, alternatives to the standard circuit model of quantum computation have been developed that have led to new quantum algorithms, breakthroughs in building quantum computers, new approaches to robustness, and significant insights into the key elements of quantum computation."

- Grover's algorithm

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"The blackbody oven embodied an... instance of radiation interacting with matter. ...Planck first... derived an empirical equation to fit the data. ...His more ambitious aim now was to find a theoretical entropy-energy connection applicable to the blackbody problem. ...Ludwig Boltzmann interpreted the second law of thermodynamics as a "probability law." If the relative probability or disorder for the state of the system was W, he concluded, then the entropy S of the system in that state was proportional to the logarithm of W,S ∝ lnW ...Plank applied this to the blackbody problem by writingS = k lnW (1)for the total entropy of the vibrating molecules... "resonators"—in the blackbody oven's walls... k is now called Boltzmann's constant. ...Boltzmann's theory taught the lesson that conceivably—but against astronomically unfavorable odds—any macroscopic process can reverse... contradicting the second law of thermodynamics. Boltzmann's conclusions seemed fantastic to Planck, but by 1900 he was becoming increasingly desparate, even reckless... The counting procedure Planck used to calculate the disorder W... was borrowed from... Boltzmann's theoretical techniques. He considered... that the total energy of the resonators was made up of small indivisible "elements," each one of magnitude ε. It was then possible to evaluate W as a count of the number of ways a certain number of energy elements could be distributed to a certain number of resonators... His argument would not succeed unless he assumed that the energy ε of the elements was proportional to the frequency with which the resonators vibrated, ε ∝ v, or ε = hv, with h the proportionality constant."

- History of quantum mechanics

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"A few years after writing the preface of that book, Popper fell into an opposite, and equally serious error about an "EPR situation," On this occasion, contrary to the preceding one, there is an over- rather than an underevaluation of the EPR analysis. On p. 27 of the same book, Popper proposes an experiment that constitutes a variant of the EPR argument, asserting that if the the Copenhagen interpretation is correct, the experiment just analyzed would allow for sending signals faster than the speed of light. This work is one of a lengthy series we will discuss later, in which it is maintained that quantum formalism would permit us to use the reduction of the wave packet to violate one of the postulates at the basis of relativity (i.e., that the speed of light cannot be exceeded). Now, despite the peculiarity of the situation addressed by EPR, this conclusion is fundamentally erroneous and arise from an incorrect use of quantum formalism. I recall a spirited discussion I once had with Popper at the International Center for Theoretical Physics at Miramare in 1983. Professor Abdus Salam informed me that on the occasion of Popper's visit (for delivering a lecture on the foundations of quantum mechanics), he would be very pleased if the Center would have on hand some competent person in the field, and asked me to take part in the discussion. I knew Popper's work well and told Professor Salam that my intervention could be critical. Salam's reply was simple: "I have full confidence in you, and if you think you are right, you should explain your position without any fear." Popper presented his thought experiment (a variant of the EPR argument), which, according to him, left us with only two alternatives: either the orthodox interpretation was correct, and it would then be possible to send signals faster than the speed of light, or there would not be any action at a distance and the experiment would constitute a falsification of quantum theory. At the end of the conference I explained to him in simple, but mathematically precise terms, the reasons why his point of departure was erroneous: he had not correctly applied the rules of the theory and in fact, the impossibility of sending superluminal signals would confirm the theory rather than falsify it—the exact opposite of what he maintained. At the end of my intervention he only said that he could not answer my objection since he did not have a mastery of the mathematics of the formalism, but was still convinced that the theory implied the possibility of superluminal signals. This strange, and, as we shall see, fundamentally erroneous idea has been supported by various researchers in various scientific works, and published in prestigious journals."

- Popper's experiment

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"When we measure a real dynamical variable ξ, the disturbance involved in the act of measurement causes a jump in the state of the dynamical system. From physical continuity, if we make a second measurement of the same dynamical variable ξ immediately after the first, the result of the second measurement must be the same as that of the first. Thus after the first measurement has been made, there is no indeterminacy in the result of the second. Hence, after the first measurement has been made, the system is in an eigenstate of the dynamical variable ξ, the eigenvalue it belongs to being equal to the result of the first measurement. This conclusion must still hold if the second measurement is not actually made. In this way we see that a measurement always causes the system to jump into an eigenstate of the dynamical variable that is being measured, the eigenvalue this eigenstate belongs to being equal to the result of the measurement. We can infer that, with the dynamical system in any state, any result of a measurement of a real dynamical variable is one of its eigenvalues. Conversely, every eigenvalue is a possible result of a measurement of the dynamical variable for some state of the system, since it is certainly the result if the state is an eigenstate belonging to this eigenvalue. This gives us the physical significance of eigenvalues. The set of eigenvalues of a real dynamical variable are just the possible results of measurements of that dynamical variable and the calculation of eigenvalues is for this reason an important problem."

- Measurement in quantum mechanics

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"An electronic semiconductor is typically a valence crystal whose conductivity depends markedly on temperature and on the presence of minute amounts of foreign impurities. The ideal crystal at the absolute zero is an insulator. When the valence bonds are completely occupied and there are no extra electrons in the crystal, there is no possibility for current to flow. Charges can be transferred only when imperfections are present in the electronic structure, and these can be of two types: excess electrons which do not fit into the valence bonds and can move through the crystal, and holes, places from which electrons are missing in the bonds, which also behave as mobile carriers. While the excess electrons have the normal negative electronic charge -e, holes have a positive charge, +e. It is a case of two negatives making a positive ; a missing negative charge is a positive defect in the electron structure. The bulk of a semiconductor is electrically neutral; there are as many positive charges as negative. In an intrinsic semiconductor, in which current carriers are created by thermal excitation, there are approximately equal numbers of excess electrons and holes. Conductivity in an extrinsic semiconductor results from impurity ions in the lattice. In n-type material, the negative charge of the excess electrons is balanced by a net positive space charge of impurity ions. In p-type, the positive charge of the holes is balanced by negatively charged impurities. Foreign atoms which can become positively charged on introduction to the lattice are called donors; atoms which become negatively ionized are called acceptors. Thus donors make a semiconductor n-type, acceptors p-type. When both donors and acceptors are present, the conductivity type depends on which is in excess. Mobile carriers then balance the net space charge of the impurity ions."

- Semiconductor

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"A powerful method to study the properties of a system is to subject it to a weak external perturbation and to examine its response. For the atomic nucleus subjected to the absorption of a photon or to the scattering of a particle (electron, proton, etc.) the response is ... a function of the energy and linear momentum transferred to the system. ... Up to about 10 MeV the nucleus responds through the excitation of relatively simple states often involving only one or a few particles. In the energy range between 10 and 30 MeV the system response exhibits broad resonances. These are the giant resonances ... Giant resonances correspond to a collective motion involving many if not all the particles in the nucleus. The occurrence of such a collective motion is a common feature of many-body quantum systems. In quantum-mechanical terms the resonance corresponds to a transition between the ground state and the collective state and its strength is described by a transition amplitude. Intuitively it is clear that the strength of the transition will depend on the basic properties of the system such as the number of particles participating in the response and the size of the system. This implies that the total transition strength should be limited by a sum rule which depends 'only' on ground-state properties. If the transition strength of an observed resonance exhausts a major part, say greater than 50%, of the corresponding sum rule we call it a giant resonance."

- Giant resonance

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