Spectroscopy

"To try to make a model of an atom by studying its spectrum is like trying to make a model of a grand piano by listening to the noise it makes when thrown downstairs."

"Plans for the final assault on Big Brother had already been worked out and agreed upon with Mission Control. Leonov would move in slowly, probing at all frequencies, and with steadily increasing power — constantly reporting back to Earth at every moment. When final contact was made, they would try to secure samples by drilling or laser spectroscopy; no one really expected these endeavours to succeed, as even after a decade of study TMA-1 resisted all attempts to analyse its material. The best efforts of human scientists in this direction seemed comparable to those of Stone Age men trying to break through the armour of a bank vault with flint axes."

"...and so recent are our best contrivances, that use has not dulled our joy and pride in them; and we pity our fathers for dying before steam and galvanism, sulphuric ether and ocean telegraphs, photograph and spectroscope arrived, as cheated out of half their human estate."

"In a certain sense I made a living for five or six years out of that one star [ υ Sagittarii ] and it is still a fascinating, not understood, star. It’s the first star in which you could clearly demonstrate an enormous difference in chemical composition from the sun. It had almost no hydrogen. It was made largely of helium, and had much too much nitrogen and neon. It’s still a mystery in many ways … But it was the first star ever analysed that had a different composition, and I started that area of spectroscopy in the late thirties."

"An attempt to study the evolution of living organisms without reference to cytology would be as futile as an account of stellar evolution which ignored spectroscopy. - J.B.S. Haldane.]]"

"Spectroscopy is a powerful tool for studying biological systems. It often provides a convenient method for analysis of individual components in a biological system such as proteins, nucleic acids, and metabolites. It can also provide detailed information about the structure and mechanism of action of molecules."

"Spectroscopy is basically an experimental subject and is concerned with the absorption, emission or scattering of electromagnetic radiation by atoms or molecules. … electromagnetic radiation covers a wide wavelength range, from radio waves to γ-rays, and the atoms or molecules may be in the gas, liquid or solid phase or, of great importance in surface chemistry, adsorbed on a solid surface. … Experimental methods of spectroscopy began in the more accessible visible region of the electromagnetic spectrum where the eye could be used as the detector."

"One important object of this original spectroscopic investigation of the light of the stars and other celestial bodies, namely to discover whether the same chemical elements as those of our earth are present throughout the universe, was most satisfactorily settled in the affirmative."

"The identification of chemical atoms in stellar atmospheres is, in fact, is accomplished thousands of times a year in numerous observations. It is interesting to recall that such an achievement was considered for ever outside the boundary of human activates. A hundred years ago, Auguste Comte, … a great French philosopher, said that “we shall never be able to study the chemical composition of The celestial bodies”. His was an encyclopedic mind but it did not encompass the potentialities of the spectroscope."

"I learned about X-ray diffraction, neutron scattering, raman scattering, infrared absorption spectroscopy, heat capacity, transport, time-dependent transport, magnetic resonance, electron diffraction, electron energy loss spectroscopy — all the experimental techniques that constitute the eyes and ears of modern solid state physics. As this occurred I slowly became disillusioned with the reductionist ideal of physics, for it was completely clear that the outcome of these experiments was almost always impossible to predict from first principles, yet was right and meaningful and certainly regulated by the same microscopic laws that work in atoms. Only many years later did I finally understand that this truth, which seems so natural to solid state physicists because they confront experiments so frequently, is actually quite alien to other branches of physics and is vigorously repudiated by many scientists on the grounds that things not amenable to reductionist thinking are not physics."

"In the heavens we discover [by spectroscopy] by their light, and by their light alone stars so distant from each other that no material thing can have ever have passed from one to another and yet this light, which is to us the sole evidence of the existence of these distant worlds, tell us also that each of them is built of molecules of the same kind as those which we find on earth. A molecule of hydrogen, for example, whether in Sirius or in Arcturus, executes its vibrations in precisely the same time. Each molecule therefore throughout the universe bears impressed upon it the stamp of a metric system as distinctly as does the metre of the Archives at Paris, or the royal cubit of the Temple of Karnac."

"The whole subject of the X rays is opening out wonderfully, Bragg has of course got in ahead of us, and so the credit all belongs to him, but that does not make it less interesting. We find that an X ray bulb with a platinum target gives out a sharp line spectrum of five wavelengths which the crystal separates out as if it were a diffraction grating. In this way one can get pure monochromatic X rays. Tomorrow we search for the spectra of other elements. There is here a whole new branch of spectroscopy, which is sure to tell one much about the nature of an atom."

"We believe that our application of terahertz technologies can provide a breakthrough in detection and identification of chemicals for homeland-security applications. Our work will further the application of terahertz spectroscopy and transmitters to meet stringent field requirements and applications."

"What we are nowadays hearing of the language of spectra is a true 'music of the spheres' in order and harmony that becomes ever more perfect in spite of the manifold variety. The theory of spectral lines will bear the name of Bohr for all time. But yet another name will be permanently associated with it, that of Planck. All integral laws of spectral lines and of atomic theory spring originally from the quantum theory. It is the mysterious organon on which Nature plays her music of the spectra, and according to the rhythm of which she regulates the structure of the atoms and nuclei."

"The matter which we suppose to be the main constituent of the universe is built out of small self-contained building-blocks, the chemical atoms. It cannot be repeated too often that the word "atom" is nowadays detached from any of the old philosophical speculations: we know precisely that the atoms with which we are dealing are in no sense the simplest conceivable components of the universe. On the contrary, a number of phenomena, especially in the area of spectroscopy, lead to the conclusion that atoms are very complicated structures. So far as modern science is concerned, we have to abandon completely the idea that by going into the realm of the small we shall reach the ultimate foundations of the universe. I believe we can abandon this idea without any regret. The universe is infinite in all directions, not only above us in the large but also below us in the small. If we start from our human scale of existence and explore the content of the universe further and further, we finally arrive, both in the large and in the small, at misty distances where first our senses and then even our concepts fail us."

"Infrared spectroscopy involves the interaction of a molecule with electro­ magnetic radiation. When an organic molecule is irradiated with infrared energy, certain frequencies are absorbed by the molecule. The frequencies absorbed correspond to the amounts of energy needed to increase the amplitude of specific molecular vibrations such as bond stretchings and bendings. Since every functional group has a characteristic combination of bonds, every functional group has a characteristic set of infrared absorptions."

"The wavelength necessary to effect the π → π* transition in a conjugated molecule depends on the energy gap between HOMO and LUMO, which in turn depends on the nature of the conjugated system. Thus, by measuring the UV spectrum of an unknown, we can derive structural information about the nature of any conjugated π electron system present in a molecule."

"This circumstance of an expanding universe is irritating. ...To admit such possibilities seems senseless to me."

"If a distant galaxy is moving relative to us, its entire is Doppler-shifted in frequency. Its s are displaced relative to those of stationary light sources. Thanks to this effect, we know that distant galaxies recede from the solar system at speeds proportional to their distances from us. That's the effect that told us of the expanding universe, and of its birth, long ago, in the Big Bang."

"All kinds of questions remain. Many have to do with cosmology. How did the universe originate? How did the galaxies become distributed in space like the suds in the kitchen sink..? Why is the cosmological constant apparently very tiny but non-zero and has a peculiar value that leads the universe to expand more rapidly?"

"All of this picture of the expansion is exciting, pleasant, coherent, well in order. But what if the s are not to be interpreted by the Doppler-Fizeau law in the classical mechanical view, or general relativistically, by the fact that the ratio of the of a photon (as measured by a co-moving observer) to the space radius of curvature is independent of ? Not speaking of quasars, the first indications for non-Doppler redshifts for a galaxy have been provided... What if not all galaxies were formed at the dawn of the Big Bang; what if some are being formed now? Then, at least, the can be anything larger than the age of our own Galaxy..."

"Red-shifts are produced either in the nebulae, where the light originates, or in the intervening space through which the light travels. If the source is in the nebulae, then red-shifts are probably velocity-shifts and the nebulae are receding. If the source lies in the intervening space, the explanation of red-shifts is unknown, but the nebulae are sensibly stationary."

"A book, too, can be a star, explosive material, capable of stirring up fresh life endlessly, a living fire to lighten the darkness, leading out into the expanding universe."

"The definition of inflation is extraordinarily simple: it is any period of the Universe's evolution during which the scale factor, describing the size of the Universe, is accelerating. This leads to a very rapid expansion of the Universe, though perhaps a better way of thinking of this is that the characteristic scale of the Universe, given by the Hubble length, is shrinking relative to any fixed scale caught up in the rapid expansion. In that sense, inflation is actually akin to zooming in on a small part of the initial Universe."

"One of the few authors to have explicitly connected the physical issue of the expansion of the universe with the philosophical topic of the metaphysical status of space is Gerald James Whitrow."

"In 1917 de Sitter showed that Einstein's field equations could be solved by a model that was completely empty apart from the cosmological constant—i.e. a model with no matter whatsoever, just . This was the first model of an expanding universe. although this was unclear at the time. The whole principle of general relativity was to write equations for physics that were valid for all observers, independently of the coordinates used. But this means that the same solution can be written in various different ways... Thus de Sitter viewed his solution as static, but with a tendency for the rate of ticking clocks to depend on position. This phenomenon was already familiar in the form of gravitational ... so it is understandable that the de Sitter effect was viewed in the same way. It took a while before it was proved (by Weyl, in 1923) that the prediction was of a redshifting of spectral lines that increased linearly with distance (i.e. ). ..."

"This model of the expanding universe I shall call the substratum. It achieves in the private Euclidean space of each fundamental observer the objects for which Einstein developed his closed spherical space. Although it is finite in volume, in the measures of any chosen observer, it has all the properties of an infinite space in that its boundary is forever inaccessible and its contents comprise an infinity of members. It is also homogeneous in the sense that each member stands in the same relation to the rest. This description of the substratum holds good in the scale of time in which the galaxies or fundamental particles are receding from one another with uniform velocities. This choice of the scale of time, together with the theory of equivalent time-keepers... makes possible the application of the Lorentz formulae to the private Euclidean spaces of the various observers. It thus brings the theory of the expanding universe into line with other branches of physics, which use the Lorentz formulæ and adopt Euclidean private spaces. ...[T]here is no more need to require a curvature for space itself in the field of cosmology than in any other department of physics. The observer at the origin is fully entitled to select a private Euclidean space in which to describe phenomena, and when he concedes a similar right to every other equivalent observer and imposes the condition of the same world-view of each observer, he is inevitably led to the model of the substratum which we have discussed."

"The ideas that prove to be of lasting interest are likely to build on the framework of the now standard world picture, the hot big bang model of the expanding universe. The full extent and richness of this picture is not as well understood as I think it ought to be, even among those making some of the most stimulating contributions to the flow of ideas."

"We should, of course, expect that any universe which expands without limit will approach the empty de Sitter case, and that its ultimate fate is a state in which each physical unit—perhaps each nebula or intimate group of nebulae—is the only thing which exists within its own observable universe."

"If the general picture, however, of a Big Bang followed by an expanding Universe is correct, what happened before that? Was the Universe devoid of all matter and then the matter suddenly somehow created? How did that happen? In many cultures, the customary answer is that a God or Gods created the Universe out of nothing. But if we wish to pursue this question courageously, we must of course ask the next question: where did God come from? If we decide that this is an unanswerable question, why not save a step and conclude that the origin of the Universe is an unanswerable question? Or, if we say that God always existed, why not save a step, and conclude that the Universe always existed? That there's no need for a creation, it was always here. These are not easy questions. Cosmology brings us face to face with the deepest mysteries, questions that were once treated only in religion and myth."

"The most far-reaching implication of general relativity... is that the universe is not static, as in the orthodox view, but is dynamic, either contracting or expanding. Einstein, as visionary as he was, balked at the idea... One reason... was that, if the universe is currently expanding, then... it must have started from a single point. All space and time would have to be bound up in that "point," an infinitely dense, infinitely small "singularity." ...this struck Einstein as absurd. He therefore tried to sidestep the logic of his equations, and modified them by adding... a "cosmological constant." The term represented a force, of unknown nature, that would counteract the gravitational attraction of the mass of the universe. That is, the two forces would cancel... it is the kind of rabbit-out-of-the-hat idea that most scientists would label ad-hoc. ...Ironically, Einstein's approach contained a foolishly simple mistake: His universe would not be stable... like a pencil balanced on its point."

"The cosmological constant['s]... most important consequence: the repulsive force, acting at cosmological distances, causes space to expand exponentially. There is nothing new about the universe expanding, but without a cosmological constant, the rate of expansion would gradually slow down. Indeed, it could even reverse itself and begin to contract, eventually imploding in a giant cosmic crunch. Instead, as a consequence of the cosmological constant, the universe appears to be doubling in size about every fifteen billion years, and all indications are that it will do so indefinitely."

"De Sitter proposed three types of nonstatic universes: the oscillating universes and the expanding universes of the first or second kiind. The main characteristic of the expanding "family" of the first kiind is that the radius is continually increasing from a definite initial time when it had the value zero. The universe becomes infinitely large after an infinite time. In the second kind... the radius possesses at the initial time a definite minimum value... in the Einstein model... the cosmological constant is supposed to be equal to the reciprocal of R2, whereas de Sitter computed for his interpretation the constant to be equal to 3/R2. Whitrow correctly points out the significant fact that in special relativity the cosmological constant is omitted..."

"[W]e stress... the wide range of validity exhibited by s in theoretical physics. ...[I]t has ...been demonstrated how they can be employed to derive equations of optics, dynamics of particles and rigid bodies, and electromagnetism. In addition, physicists have succeeded in formulating the laws of elasticity and hydrodynamics as variational principles, and even Einstein's law of gravitation was included in this category by Hilbert, who found a scaler function... for which \partial\int\mathfrak{h}\,dx_0\,dx_1\,dx_2\,dx_3=0 is equivalent to Einstein's law. This function has been called the "curvature," an identification which induced Whittaker to describe Hilbert's principle in the laconic words, "gravitation simply represents a continual effort of the universe to straighten itself out.""

"The general theory of relativity considers physical space-time as a four-dimensional manifold whose line element coefficients g_{\mu \nu} satisfy the differential equationsG_{\mu \nu} = \lambda g_{\mu \nu} \qquad .\;.\;.\;.\;.\;.\; (1)in all regions free from matter and electromagnetic field, where G_{\mu \nu} is the contracted Riemann-Christoffel tensor associated with the fundamental tensor g_{\mu \nu}, and \lambda is the ."

"An "empty world," i.e., a homogeneous manifold at all points at which equations (1) are satisfied, has, according to the theory, a constant Riemann curvature, and any deviation from this fundamental solution is to be directly attributed to the influence of matter or energy."

"In considerations involving the nature of the world as a whole the irregularities caused by the aggregation of matter into stars and stellar systems may be ignored; and if we further assume that the total matter in the world has but little effect on its macroscopic properties, we may consider them as being determined by the solution of an empty world."

"The solution of (1), which represents a homogeneous manifold, may be written in the form:ds^2 = \frac{d\rho^2}{1 - \kappa^2\rho^2} - \rho^2 (d\theta^2 + sin^2 \theta \; d\phi^2) + (1 - \kappa^2 \rho^2)\; c^2 d\tau^2, \qquad (2)where \kappa = \sqrt \frac{\lambda}{3}. If we consider \rho as determining distance from the origin... and \tau as measuring the proper-time of a clock at the origin, we are led to the de Sitter spherical world..."

"O. Heckmann has pointed out that the non-static solutions of the field equations of the general theory of relativity with constant density do not necessarily imply a positive curvature of three-dimensional space, but that this curvature may also be negative or zero. There is no direct observational evidence for the curvature, the only directly observed data being the mean density and the expansion, which latter proves that the actual universe corresponds to the non-statical case. It is therefore clear that from the direct data of observation we can derive neither the sign nor that value of the curvature, and the question arises whether it is possible to represent the observed facts without introducing the curvature at all. Historically the term containing the "cosmological constant" λ was introduced into the field equations in order to enable us to account theoretically for the existence of a finite mean density in a static universe. It now appears that in the dynamical case this end can be reached without the introduction of λ."

"The determination of the coefficient of expansion h depends on the measured red-shifts, which do not introduce any appreciable uncertainty, and the distances of the extra-galactic nebulae, which are still very uncertain. The density depends on the assumed masses of these nebulae and on the scale of distance, and involves, moreover, the assumption that all the material mass in the universe is concentrated in the nebulae. It does not seem probable that this latter assumption will introduce any appreciable factor of uncertainty."

"Although... the density... corresponding to the assumption of zero curvature and to the coefficient of expansion... may perhaps be on the high side, it... is of the correct order of magnitude, and we must conclude that... it is possible to represent the facts without assuming a curvature of three-dimensional space. The curvature is, however, essentially determinable, and an increase in the precision of the data derived from observations will enable us in the future to fix its sign and to determine its value."

"Why should not the space be there already, and the material system expand into it..? ...[I]f the speed of recession continues to increase outwards, it will ere long approach the speed of light, so that something must break down. The result is that the system becomes a ... such a system cannot expand without the space also expanding. ...[E]xpansion of space has often been given too much prominence ...and readers have been led to think that it is more directly concerned in the explanation of the motions of the nebule than is... the case. ...If we adopt open space we encounter certain difficulties (not necessarily insuperable) which closed space entirely avoids; and we do not want... speculation as to the solution of difficulties which need never arise. If we wish to be noncommittal, we shall naturally work in terms of a closed universe of finite radius R, since we can at any time revert to an infinite universe by making R infinite."

"The immediate results of introducing the cosmical term into the law of gravitation was the appearance... of two universes—the Einstein universe and the de Sitter universe. Both were closed spherical universes; so that a traveller going on and on in the same direction would at last find himself back at the starting-point... Both claimed to be static universes... thus they provided a permanent framework within which the small-scale systems—galaxies and stars—could change and evolve. ...[H]owever ...in de Sitter's universe there would be an apparent recession of remote objects ...At that time only three radial velocities were known, and these ...lamely supported de Sitter ...2 to 1. ...But in 1922 ...V. M. Sipher furnished me ...measures of 40 spiral nebulæ for ...my book Mathematical Theory of Relativity. ...[T]he majority had become 36 to 4 ..."

"The situation has been summed up in the statement that Einstein’s universe contains matter but no motion and de Sitter’s contains motion but no matter. ...[T]he actual universe containing both matter and motion does not correspond exactly to either... Which is the better choice for a first approximation? Shall we put a little motion into Einstein’s world of inert matter, or... a little matter into de Sitter’s ?"

"The choice between Einstein’s and de Sitter’s models... [W]e are not now restricted to these... extremes; we have... the whole chain of intermediate solutions between motionless matter and matterless motion... [W]e can pick... the right proportion of matter and motion to correspond with what we observe. ...[E]arlier... it was the preconceived idea that a static solution was a necessity... an unchanging background of space. ...[T]his ...should strictly have barred... de Sitter’s solution, but ...it was the precursor of the other non-static solutions..."

"[I]nvestigation of non-static solutions was carried out by A. Friedmann in 1922. His solutions were rediscovered in 1927 by Abbé G. Lemaître, who brilliantly developed the astronomical theory... and... remained unknown until 1930... In the meantime the solutions had been discovered... by H. P. Robertson, and through him... interest was... realised. The astronomical application, stimulated by Hubble and Humason’s observational work on the spiral nebule, was also being rediscovered, but it had not been carried so far as in Lemaître’s paper."

"The intermediate solutions of Friedmann and Lemaitre are "expanding universes." Both the material system and the closed space, in which it exists, are expanding. At one end we have Einstein’s universe with no motion and therefore in equilibrium. Then... we have model universes showing more and more rapid expansion until we reach de Sitter’s... The rate of expansion increases all the way along the series and the density diminishes; de Sitter’s universe is the limit when the average density of celestial matter approaches zero. The series of expanding universes then stops... but because there is nothing left to expand."

"[T]he most satisfying theory would be one which made the beginning not too unæsthetically abrupt. This... can only be satisfied by an Einstein universe with all... major forces balanced. Accordingly, the primordial state of things... is an even distribution of s and electrons, extremely diffuse and filling all (spherical) space, remaining nearly balanced for an exceedingly long time until its inherent instability prevails. ...[T]he density of this distribution can be calculated ...[at] about one proton and electron per litre. ...[S]mall irregular tendencies accumulate, and evolution gets under way. ...[T]he formation of condensations ultimately ...become the galaxies; this ...started off an expansion, which ...automatically increased in speed until ...now manifested ...in the recession of the spiral nebulae. As the matter drew closer... in the condensations... evolutionary processes followed—evolution of stars... of... more complex elements... of planets and life."

"Within the galaxy the average world-curvature is... thousands of times greater than Lamaître's average for the universe... his formulæ are inapplicable. The result... only the intergalactic distances expand. The galaxies... are unaffected... —s, stars, human observers and their apparatus, atoms—are entirely free from expansion. Although the cosmical repulsion or expansive tendency is present in all of these... it is checked by much larger forces... [T]he demarcation between permanent and dispersing systems is... abrupt. It corresponds to the distinction between periodic and aperiodic phenomena."

"If you think... the shattering of the bubble universe is... tragic... [W]hen the worst has happened our galaxy... will be left intact. ...not so bad a prospect."

"All change is relative. The universe is expanding relatively to our common material standards; our material standards are shrinking relatively to the size of the universe. The theory of the "expanding universe" might also be called the theory of the "shrinking atom". ...[T]ake the... universe as our standard of constancy... he sees us shrinking... only the intergalactic spaces remain the same. The earth spirals round the sun in an ever‑decreasing orbit. ...Our years will ...decrease in geometrical progression in the cosmic scale of time. ... Owing to the property of geometrical progressions an infinite number of our years will add up to a finite cosmic time; so that what we should call the end of eternity is an ordinary finite date in the cosmic calendar. But on that date the universe has expanded to infinity in our reckoning, and we have shrunk to nothing in the reckoning of the cosmic being. ...When the last act opens the curtain rises on midget actors rushing through their parts at frantic speed. Smaller and smaller. Faster and faster. One last microscopic blurr of intense agitation. And then nothing."

"If the astronomers are right, it is a straightforward conclusion from the observational measurements that the system of galaxies is expanding—or, since the system of the galaxies is all we know—that the universe is expanding. There is no subtlety or metaphysics about it ...But are we sure of the observational facts? Scientific men are rather fond of saying pontifically that one ought to be quite sure of one's observational facts before embarking on theory. Fortunately those who give this advice do not practice what they preach. Observation and theory get on best when they are mixed together, both helping one another in the pursuit of truth. It is a good rule not to put overmuch confidence in a theory until it has been confirmed by observation. I hope I shall not shock the experimental physicists too much if I add that it is also a good rule not to put overmuch confidence in the observational results that are put forward until they have been confirmed by theory. So in starting to theorise about the expanding universe I am not taking it for granted that the observational evidence which we have been considering is entirely certain."

"It is scarcely true... that we observe these velocities of recession. We observe a shift of the spectrum to the red; and although such... is usually due to recession... it is not inconceivable that it should arise from another cause."

"[I]t was theory that first suggested a systematic recession of the spiral nebulae and so led to a search for this effect. The theoretical possibility was first discovered by W. de Sitter in 1917. Only three radial velocities were known at that time, and they... lamely supported his theory by... 2 to 1. Since then... support is far more unanimous... mainly due to V. M. Slipher... and M. L. Humason... The linear law of proportionality between speed and distance was found by E. H. Hubble. Meanwhile the theory has also developed, and... taken the form... associated with... A. Friedman and G. Lemaître."

"The theory of relativity predicts... a... force... we call the cosmical repulsion... directly proportional to the distance... It is so weak... we can leave it out of... motions of the planets... or any motion within... our... galaxy. ...[S]ince it increases... to the distance we... if we go far enough, find it significant."

"I have said the repulsion is proportional to the distance... Distance from what? From anywhere you like. ...Cosmical repulsion is a dispersing force tending to make a system expand uniformly—not diverging from any centre in particular, but such that all internal distances increase at the same rate. That corresponds precisely to the kind of expansion we observe in the system of the galaxies."

"I have said that relativity theory predicts a force of cosmical repulsion. ...[R]elativity theory does not talk of anything so crude as force; it describes... curvature of space-time. But for practical purposes... nearly equivalent to the Newtonian force of gravitation... [T]he actual relativity effect is represented with sufficient accuracy by a force of cosmical repulsion... up to the greatest distances... we... observe."

"The galaxies exert on one another their ordinary gravitational attraction approximately according to Newton's law. This makes them tend to cling together. So we... have a contest of two forces, Newtonian attraction... and cosmical repulsion... If our theory is right cosmical repulsion must have got the upper hand... Having got the advantage, cosmical repulsion will keep it; because, as the nebulae become further apart, their mutual attraction will become weaker..."

"is a congruence geometry, or equivalently the space comprising its elements is homogeneous and isotropic; the intrinsic relations between... elements of a configuration are unaffected by the position or orientation of the configuration. ...[M]otions of are the familiar translations and rotations... made in proving the theorems of Euclid."

"[O]nly in a homogeneous and isotropic space can the traditional concept of a rigid body be maintained."

"That the existence of these motions (the "axiom of free mobility") is a desideratum, if not... a necessity, for a geometry applicable to physical space, has been forcefully argued on a priori grounds by von Helmholtz, Whitehead, Russell and others; for only in a homogeneous and isotropic space can the traditional concept of a rigid body be maintained."

"Euclidean geometry is only one of several congruence geometries... Each of these geometries is characterized by a real number K, which for Euclidean geometry is 0, for the hyperbolic negative, and for the spherical and elliptic geometries, positive. In the case of 2-dimensional congruence spaces... K may be interpreted as the ' of the surface into the third dimension—whence it derives its name..."

"[W]e propose... to deal exclusively with properties intrinsic to the space... measured within the space itself... in terms of... inner properties."

"Measurements which may be made on the surface of the earth... is an example of a 2-dimensional congruence space of positive curvature K = \frac{1}{R^2}... [C]onsider... a "small circle" of radius r (measured on the surface!)... its perimeter L and area A... are clearly less than the corresponding measures 2\pi r and \pi r^2... in the Euclidean plane. ...for sufficiently small r (i.e., small compared with R) these quantities on the sphere are given by 1):L = 2 \pi r (1 - \frac{Kr^2}{6} + ...), A = \pi r^2 (1 - \frac{Kr^2}{12} + ...)"

"In the sum \sigma of the three angles of a triangle (whose sides are arcs of s) is greater than two right angles [180°]; it can... be shown that this "spherical excess" is given by 2)\sigma - \pi = K \deltawhere \delta is the area of the spherical triangle and the angles are measured in s (in which 180° = \pi [radians]). Further, each full line (great circle) is of finite length 2 \pi R, and any two full lines meet in two points—there are no parallels!"

"[T]he space constant K... "" may in principle at least be determined by measurement on the surface, without recourse to its embodiment in a higher dimensional space."

"These formulae [in (1) and (2) above] may be shown to be valid for a circle or a triangle in the hyperbolic plane... for which K < 0. Accordingly here the perimeter and area of a circle are greater, and the sum of the three angles of a triangle are less, than the corresponding quantities in the Euclidean plane. It can also be shown that each full line is of infinite length, that through a given point outside a given line an infinity of full lines may be drawn which do not meet the given line (the two lines bounding the family are said to be "parallel" to the given line), and that two full lines which meet do so in but one point."

"The value of the intrinsic approach is especially apparent in considering 3-dimensional congruence spaces... The intrinsic geometry of such a space of curvature K provides formulae for the surface area S and the volume V of a "small sphere" of radius r, whose leading terms are 3)S = 4 \pi r^2 (1 - \frac{Kr^2}{3} + ...), V = \frac{4}{3} \pi r^3 (1 - \frac{Kr^2}{5} + ...)."

"In all these congruence geometries, except the Euclidean, there is at hand a natural unit of length R = \frac{1}{K^\frac{1}{2}}; this length we shall, without prejudice, call the "radius of curvature" of the space."

"We have merely (!) to measure the volume V of a sphere of radius r or the sum \sigma of the angles of a triangle of measured are \delta, and from the results to compute the value of K."

"What is needed is a homely experiment which could be carried out in the basement with parts from an old sewing machine and an Ingersoll watch, with an old file of Popular Mechanics standing by for reference! This I am, alas, afraid we have not achieved, but I do believe that the following example... is adequate to expose the principles..."

"Let a thin, flat metal plate be heated... so that the temperature T is not uniform... clamp or otherwise constrain the plate to keep it from buckling... [and] remain [reasonably] flat... Make simple geometric measurements... with a short metal rule, which has a certain coefficient of expansion c... What is the geometry of the plate as revealed by the results of those measurements? ...[T]he geometry will not turn out to be Euclidean, for the rule will expand more in the hotter regions... [T]he plate will seem to have a negative curvature K... the kind of structure exhibited... in the neighborhood of a ".""

"What is the true geometry of the plate? ...Anyone examining the situation will prefer Poincaré's common-sense solution... to attribute it Euclidean geometry, and to consider the measured deviations... as due to the actions of a force (thermal stresses in the rule). ...On employing a brass rule in place of one of steel we would find that the local curvature is trebled—and an ideal rule (c = 0) would... lead to Euclidean geometry."

"In what respect... does the general theory of relativity differ...? The answer is: in its universality; the force of gravitation in the geometrical structure acts equally on all matter. There is here a close analogy between the gravitational mass M...(Sun) and the inertial mass m... (Earth) on the one hand, and the heat conduction k of the field (plate)... and the coefficient of expansion c... on the other. ...The success of the general relativity theory... is attributable to the fact that the gravitational and inertial masses of any body are... rigorously proportional for all matter."

"The field equation may... be given a geometrical foundation, at least to a first approximation, by replacing it with the requirement that the mean curvature of the space vanish at any point at which no heat is being applied to the medium—in complete analogy with... the general theory of relativity by which classical field equations are replaced by the requirement that the Ricci contracted curvature tensor vanish."

"Now it is the practice of astronomers to assume that brightness falls off inversely with the square of the "distance" of an object—as it would do in Euclidean space, if there were no absorption... We must therefore examine the relation between this astronomer's "distance" d... and the distance r which appears as an element of the geometry."

"All the light which is radiated... will, after it has traveled a distance r, lie on the surface of a sphere whose area S is given by the first of the formulae (3). And since the practical procedure... in determining d is equivalent to assuming that all this light lies on the surface of a Euclidean sphere of radius d, it follows...4 \pi d^2 = S = 4 \pi r^2 (1 - \frac{K r^2}{3} + ...);whence, to our approximation 4)d = r (1- \frac{K r^2}{6} + ...), or r = d (1 + \frac{K d^2}{6} + ...)."

"[T]he astronomical data give the number N of nebulae counted out to a given inferred "distance" d, and in order to determine the curvature... we must express N, or equivalently V, to which it is assumed proportional, in terms of d. ...from the second of formulae (3) and... (4)... to the approximation here adopted, 5)V = \frac{4}{3} \pi d^2 (1 + \frac{3}{10} K d^2 + ...);...plotting N against... d and comparing... with the formula (5), it should be possible operationally to determine the "curvature" K."

"This... is an outrageously over-simplified account of the assumptions and procedures..."

"The search for the curvature K indicates that, after making all known corrections, the number N seems to increase faster with d than the third power, which would be expected in a Euclidean space, hence K is positive. The space implied thereby is therefore bounded, of finite total volume, and of a present "radius of curvature" R = \frac{1}{K^\frac{1}{2}} which is found to be of the order of 500 million light years. Other observations, on the "red shift" of light from these distant objects, enable us to conclude with perhaps more assurance that this radius is increasing..."

"Hubble was inclined, from about 1936, to reject the Doppler-effect interpretation of the red shifts and to regard the nebulae as stationary; but theoretical cosmologists, notably McVittie... and Heckmann... severely criticized Hubble’s method...and disputed his conclusions. Although these criticisms... came to be generally accepted, it still seemed that the available data were open to rival interpretations, depending on the method of analysis..."

"At last, in 1949, the... ... was ready... Humason... succeeded in photographing the spectra of two remote galaxies in the . These exhibited red-shifts which, on the Doppler interpretation, indicated... one-fifth of the velocity of light. [I]n 1956, with... photoelectric equipment attached... [W. A.] Baum obtained a red-shift... recessional velocity of about two-fifths of the velocity of light."

"[I]n... 1952, Baade... announced that Hubble’s entire distance scale was in error... According to Baade, the distances formerly assigned to all extragalactic objects must be multiplied by a factor of about two. Later it was generally accepted that this... was probably nearer three. ...[I]t followed that the sizes of all such objects had been underestimated. ...Therefore ...this nebula must be... twice as far away... [T]he average absolute magnitude at maximum brightness of novae... in the Milky Way attain on the average... 7.4, whereas those... in the Andromeda... 5.7... [T]he apparent anomaly could be removed by placing... Andromeda... rather more than twice as far as previously. ...[[w:Distance measure|[E]xtragalactic distances]] had ...been underestimated because of an error in converting... relative distances of s into an absolute scale. ...Baade's revision ...applied only to extragalactic objects... [and] had momentous consequences concerning the size and , for the scale of both was correspondingly increased."

"An important new survey of the law relating red-shifts and magnitudes published in 1956 by Humason, Mayall and Sandage suggested... that the expansion of the universe may have been faster in the past... so that its age may be somewhat less than that estimated on the hypothesis of uniform expansion. But... caution, for a recent review (1958) by Sandage of Hubble's criteria for constructing the extragalactic distance-scale has revealed that, not only must his Cepheid criterion be corrected but also... the brightest star criterion..."

"As for Hubble’s brightest star criterion, Sandage... has shown that objects in the of galaxies which Hubble believed to be highly luminous stars are... regions of glowing of intrinsic luminosity... two magnitudes brighter... If Sandage’s result is accepted, then the distances of all galaxies beyond those in which Cepheids can be detected... must be augmented by a factor... between 5 and 10... with the result that the rate of increase of velocity with distance will be reduced to between 5O and 100 kilometres per second per megaparsec. Consequently, taking 80 as a rough average... the , if it has expanded uniformly, will have to be increased to about 13-5 thousand million years. If... it was expanding more rapidly in the past... this... might be reduced to about 9 thousand million years."