Electron

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aprilie 10, 2026

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aprilie 10, 2026

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"Maxwell's equations had proved themselves incapable of accounting for dispersion. It appeared necessary to conceive of some structure for dielectrics which would act selectively, imposing different degrees of retardation on light waves of different frequencies. Lorentz achieved this result by assuming that electricity was atomic and that matter was constituted by more or less complicated groupings of these electric atoms or electrons. Phenomena were accounted for by taking into consideration the frictional resistances that would interfere with rapid vibrations of the electrons. When these frictional resistances were weak, oscillatory disturbances, such as rays of light, could be propogated through the dielectric, which was then termed transparent (glass). When these frictional forces were considerable, the light ray was unable to set the electrons into vibration; its energy was consumed in the attempt, and as a result it could not proceed; the dielectric was then opaque (ebonite, sulphur). In the case of conductors such as metals, the electrons were assumed to be very loosely held to their atoms so that the slightest difference of potential would tear them away and cause them to rush in the same direction, thereby producing an electric current. It was precisely because electrons in conductors were not tied down to fixed positions by elastic forces that they were incapable of vibrating; and so conductors were necessarily opaque to electromagnetic vibrations or to light. Conversely, it was because the electrons were all tied down to fixed positions in the dielectrics, that they could not rush along in one direction. As a result dielectrics were opaque to currents, and hence were non-conductors. According to these views of Lorentz, an electric current passing through matter was nothing but a rush of electrons."

- Electron

• 0 likes• atomic-physics• physical-chemistry•
"It must have been one evening after midnight when I suddenly remembered my conversation with Einstein and particularly his statement, "It is the theory which decides what we can observe." I was immediately convinced that the key to the gate that had been closed for so long must be sought right here. ...We had always said so glibly that the path of the electron in the cloud chamber could be observed. But perhaps what we really observed was something much less. Perhaps we merely saw a series of discrete and ill-defined spots through which the electron had passed. ...The right question should therefore be: Can quantum mechanics represent the fact that an electron finds itself approximately in a given place and that it moves approximately with a given velocity, and can we make these approximations so close that they do not cause experimental difficulties? A brief calculation after my return to the Institute showed that one could indeed represent such situations mathematically, and that the approximations are governed by what would later be called the uncertainty principle of quantum mechanics: the product of the uncertainties in the measured values of the position and momentum (i.e., the product of mass and velocity) cannot be smaller than Planck's constant. This formulation, I felt, established the much-needed bridge between the cloud chamber observations and the mathematics of quantum mechanics. True, it had still to be proved that any experiment whatsoever was bound to set up situations satisfying the uncertainty principle, but this struck me as plausible a priori, since the processes involved in the experiment or the observation had necessarily to satisfy the laws of quantum mechanics. On this presupposition, experiments are unlikely to produce situations that do not accord with quantum mechanics. "It is the theory which decides what we can observe." I resolved to prove this by calculations based on simple experiments during the next few days."

- Electron

• 0 likes• atomic-physics• physical-chemistry•
"If we wish to visualize... processes pictorially, no single picture is available, and the best we can do is to construct a number of imperfect pictures, each representing one, but only one, aspect of the complete set of phenomena. For instance, if a shower of electrons is shot on to a zinc sulfide screen, a number of flashes are produced—one for each electron—and we may picture the electrons as bullet-like projectiles hitting a target. But if the same shower is made to pass near a suspended magnet, this is found to be deflected as the electrons go by. The electrons may now be pictured as octopus-like structures with tentacles or 'tubes of force' sticking out from it in every direction. It would, however, be wrong to think of an electron as a bullet-like structure with tentacles sticking out from its surface. We can calculate the mass of the bullet, and also the mass of the tentacles. The two masses are found to be identical, each agreeing with the known mass of the electron. Thus we cannot take the electron to be bullet plus tentacles... we must take it to be bullet or tentacles. The two pictures do not depict two different parts of the electron, but two different aspects of the electron. They are not additive but alternative; as one comes into play, the other must disappear. Actually the situation is even more complicated, since a separate tentacle picture is needed for each speed of motion of the electron, the speed being measured relative to the suspended magnet or other object on which the moving electron is to act. ...When the electron is at rest, the tentacles stick out equally in all directions. But an electron which is at rest relative to one magnet may be in motion relative to another, and to discuss the action of the electron on this second magnet we must picture it as having a belt of tentacles round its waist. This shows that we must have a different picture for every speed of relative motion, so that the total number of pictures is infinite, and we cannot form the picture we need unless we know the speed of the electron relative to the object it is about to meet."

- Electron

• 0 likes• atomic-physics• physical-chemistry•
"The facts of chemical physics point to electrification being distributed in an atomic manner, so that an atom of electricity, say an electron, has the same claims to separate and permanent existence as an atom of matter. The fundamental question then is, how far the conception of separate isolated electrons, pervading the aether of free space, can provide an explanation of electrodynamic and optical phenomena. ...Whatever view one may entertain as to the presence of qualities other than electric in the atom, all are I think now-a-days agreed that the electron is there. And whatever view one may have as to the validity and sufficiency of an æther with simple rotational elasticity, the formal equations to which that theory leads for free space are just those equations of Maxwell which Hertz's experimental work has fully verified. The problem of electrodynamics is then that of the free æther, whose properties are represented analytically by these acknowledged equations, disturbed by the action of the electrons of material atoms moving about in it. The original Amperean electrodynamics, proceeding by consideration of elements of current, has not proved valid or sufficient in matters involving electric radiation, or even ordinary electrodynamic force. A most successful modification of it was that proposed by Weber in which elements of current were replaced, as the fundamental object of consideration, by moving electric particles which acted on each other at a distance according to a law of force involving their velocities. This theory was, however, shown long ago by Lord Kelvin and Professor von Helmholtz to be untenable on account of its violating the principles of the modern theory of energy; now, of course, direct action at a distance is altogether out of court. The present question is whether a theory of electrons which act on each other, not directly according to a law of force, but mediately by propagation of the effect across the intervening æther, suffices to avoid the discrepancies of earlier theories and give a consistent account of electrical and optical phenomena; and it is maintained that the answer is altogether in the affirmative."

- Electron

• 0 likes• atomic-physics• physical-chemistry•
"One has been led to the conception of electrons, i.e. of extremely small particles, charged with electricity, which are present in immense numbers in all ponderable bodies, and by whose distribution and motions we endeavor to explain all electric and optical phenomena that are not confined to the free ether. ...according to our modern views, the electrons in a conducting body, or at least a certain part of them, are supposed to be in a free state, so that they can obey an electric force by which the positive particles are driven in one, and the negative electrons in the opposite direction. In the case of a non-conducting substance, on the contrary, we shall assume that the electrons are bound to certain positions of equilibrium. If, in a metallic wire, the electrons of one kind, say the negative ones, are travelling in one direction, and perhaps those of the opposite kind in the opposite direction, we have to do with a current of conduction, such as may lead to a state in which a body connected to one end of the wire has an excess of either positive or negative electrons. This excess, the charge of the body as a whole, will, in the state of equilibrium and if the body consists of a conducting substance, be found in a very thin layer at its surface. In a ponderable dielectric there can likewise be a motion of the electrons. Indeed, though we shall think of each of them as haying a definite position of equilibrium, we shall not suppose them to be wholly immovable. They can be displaced by an electric force exerted by the ether, which we conceive to penetrate all ponderable matter... the displacement will immediately give rise to a new force by which the particle is pulled back towards its original position, and which we may therefore appropriately distinguish by the name of elastic force. The motion of the electrons in non-conducting bodies, such as glass and sulphur, kept by the elastic force within certain bounds, together with the change of the dielectric displacement in the ether itself, now constitutes what Maxwell called the displacement current. A substance in which the electrons are shifted to new positions is said to be electrically polarized. Again, under the influence of the elastic forces, the electrons can vibrate about their positions of equilibrium. In doing so, and perhaps also on account of other more irregular motions, they become the centres of waves that travel outwards in the surrounding ether and can be observed as light if the frequency is high enough. In this manner we can account for the emission of light and heat. As to the opposite phenomenon, that of absorption, this is explained by considering the vibrations that are communicated to the electrons by the periodic forces existing in an incident beam of light. If the motion of the electrons thus set vibrating does not go on undisturbed, but is converted in one way or another into the irregular agitation which we call heat, it is clear that part of the incident energy will be stored up in the body, in other terms [words] that there is a certain absorption. Nor is it the absorption alone that can be accounted for by a communication of motion to the electrons. This optical resonance, as it may in many cases be termed, can likewise make itself felt even if there is no resistance at all, so that the body is perfectly transparent. In this case also, the electrons contained within the molecules will be set in motion, and though no vibratory energy is lost, the oscillating particles will exert an influence on the velocity with which the vibrations are propagated through the body. By taking account of this reaction of the electrons we are enabled to establish an electromagnetic theory of the refrangibility of light, in its relation to the wave-length and the state of the matter, and to form a mental picture of the beautiful and varied phenomena of double refraction and circular polarization. On the other hand, the theory of the motion of electrons in metallic bodies has been developed to a considerable extent. ...important results that have been reached by Riecke, Drude and J. J. Thomson... the free electrons in these bodies partake of the heat-motion of the molecules of ordinary matter, travelling in all directions with such velocities that the mean kinetic energy of each of them is equal to that of a gaseous molecule at the same temperature. If we further suppose the electrons to strike over and over again against metallic atoms, so that they describe irregular zigzag-lines, we can make clear to ourselves the reason that metals are at the same time good conductors of heat and of electricity, and that, as a general rule, in the series of the metals, the two conductivities change in nearly the same ratio. The larger the number of free electrons, and the longer the time that elapses between two successive encounters, the greater will be the conductivity for heat as well as that for electricity."

- Electron

• 0 likes• atomic-physics• physical-chemistry•
"The modern theory of electrical and allied optical phenomena... [i.e.,] the "electron theory," means practically a return to views as laid down in the sixties and seventies by Wilhelm Weber and Zöllner, but modified by the results of Maxwell's and Hertz's researches. W. Weber imagined electric phenomena as the actions of elementary electrical particles—so called "electric atoms"—whose mutual influence depended not only upon their positions but also upon their relative velocities and accelerations. Although Weber succeeded by means of his hypothesis in completely describing the electrodynamical phenomena known at his time, and even in giving a quantitatively useful explanation of the correspondence between electric and thermal conduction in metals, as well as Ampère's molecular currents in magnets, still his theory was far from becoming the common property of physicists of his day. The reason for this negative success may be sought for in the fact that most of the laws of electrodynamics when expressed from the standpoint of pure phenomenology in the shape of differential equations, are much more simple and convenient than Weber's formulæ. In addition, Weber makes no attempt to calculate the size of his electrical atoms and to test the result... And, finally, the work of Faraday and Maxwell brought about a general feeling that in electric and magnetic phenomena a finite rate of propagation would have to take the place of action at a distance. This demand was already put forward by Gauss in letter to Weber in 1845..."

- Electron

• 0 likes• atomic-physics• physical-chemistry•
"Maxwell's treatises, begun in 1861-62 and concluded in 1873 in his famous "Treatise on Electricity and Magnetism," as well as the brilliant experimental confirmation of Maxwell's results by H. Hertz from 1887, seemed calculated to deprive Weber's views of the last vestige of vitality. ...Maxwell's formulæ, wholly void as they were of atomistic conceptions, represented the fundamental electrical phenomena just as well as the old conceptions based upon action at a distance, and the newly-discovered Hertzian waves could only be represented by Maxwell's theory. ...this brilliant success had at first blinded physicists with regard to the insufficiency of Maxwell's theory in... optical phenomena. According to Maxwell... the vibrations of light were not mechanical, but electrical vibrations of the ether, and the two constants by which Maxwell defined the electric and magnetic behaviour of every body (the dielectric constant and the magnetic permeability) had also to be the determining elements in its refractive power. Although the condition demanded by Maxwell—of the refractive power varying as the square root of the dielectric constant—was well fulfilled in a number of bodies, yet... many bodies, notably water, showed... enormous deviations... To this was added the dependence of the refractive index upon the colour [frequency], for which the original theory gave no explanation whatever."

- Electron

• 0 likes• atomic-physics• physical-chemistry•
"The next question is: What reason have we for assuming presence of electric particles in every transparent body? The answer is furnished by a set of phenomena which hardly fitted into Maxwellian theory, and which was, therefore, almost always in accordance with the old views. I refer to the phenomena of electrolysis. When the electric current traverses an electrolyte, then, according to Faraday's law, every unit of current deposits chemically equivalent masses at the electrode. We may, therefore, assume that every chemical equivalent of an ion wandering in electrolyte is attached to definite and unchangeable positive or negative quantity of electricity. In his Faraday Memorial Address of 1881 Helmholtz points out that Faraday's law necessarily implies the existence of electric atoms. For since the charged chemical atoms called by ions (i.e., wanderers) are liberated at the electrodes as neutral bodies, there must be a giving up of the charges or a partial exchange with charges of opposite sign. During this process, which cannot instantaneous, the charges must, therefore, be capable of existence during a short time at least. It obviously suggests itself to regard this always uniform unit charge as an elementary quantity of electricity, as an "electric atom." And when a neutral molecule—say NaCl—splits up in +Na and -CI when dissolved in water, it is most probable that both the sodium and the chlorine atom had their charges beforehand, and that these charges were not appreciable [apparent] because they were equal and opposite. But if we consider a ray of light traversing a crystal of salt, the charges and the atoms they accompany must be thrown into vibrations, and must influence the propagation of the light. It is, therefore, the electrolytic valency charges which we have to regard as the electric particles vibrating a transparent body, and whose attractive forces, as Helmholtz showed, probably constituted the greatest part of the forces of chemical affinity."

- Electron

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