Phlogiston theory

"It is commonly stated that the exception is a proof of the rule. The history of science can show many instances whereby the rule has been demolished by the exception. Little facts have killed big "theories, even as a pebble has slain a giant. During the reign of phlogiston a few of such facts were not unknown at least to some of the better informed of Stahl's followers."

"Some of the alchemists had discovered that a metal gained, not lost, weight by . This was known as far back as the sixteenth century. It had been pointed out by Cardan and by Libavius. Sulzbach showed that such was the case with mercury. Boyle proved it in the case of tin, and Rey in that of lead. Moreover, as knowledge increased it became certain that Stahl's original conception of the principle of combustion as a ponderable substance he imagined, with Becher, that it was of the nature of an earth was not tenable. The later phlogistians were disposed to regard it as probably identical with . But even hydrogen has weight, and facts seemed to require that phlogiston, if it existed at all, should be devoid of weight."

"Towards the latter half of the eighteenth century clearer views began to be held concerning the relations of atmospheric air to the phenomena of combustion and of calcination; many half-forgotten facts relating to these phenomena were recalled, and the inconsistencies and insufficiency of phlogiston as a dogma became gradually manifest. Three cardinal facts conspired to bring about its overthrow—the isolation of oxygen by Priestley; the recognition by him of the nature of atmospheric air, and of the fact that one of its constituents is oxygen; and, lastly, the discovery by Cavendish that water is a compound, and that its constituents are oxygen and . The significance of these facts was first clearly grasped by Lavoisier, and to him is due the credit of their true interpretation. By reasoning and experiment he proved conclusively that all ordinary phenomena of burning are so many instances of the combination of the oxygen of the air with the combustible substance; that calcination is a process of combination of the oxygen in the air with the metal, which thereby increases in weight by the amount of oxygen combined. Water no longer a simple substance is formed by the union, weight for weight, of oxygen and hydrogen. ...The phlogiston myth was thus exploded."

"Inspired by Lavoisier, a small band of French chemists Berthollet, Fourcroy, Guyton de Morveau thereupon set to work to remodel the system of chemistry and to recast its nomenclature so as to eliminate all reference to phlogiston. The very names "oxygen," "hydrogen," "nitrogen," corresponding respectively to the "dephlogisticated air," "phlogiston," and "phlogisticated air" of Priestley, were coined by the new French school."

"For a time le principe oxygine was regarded by this school in much the same relation as phlogiston was regarded by Stahl and his followers. The one fetich was exchanged for the other. The combustible principle—phlogiston—was renounced for the acidifying principle—oxygen. The new chemistry for a time centred itself round oxygen, just as the old chemistry had centred itself round phlogiston. The views of the French school met with no immediate acceptance in Germany, the home of phlogistonism, or in Sweden or England, possibly owing, to some extent, to national prejudices. The spirit of revolution, even although it might be an intellectual revolution, had not extended to these countries. Priestley, Cavendish, and Scheele could not be induced to accept the new doctrine. It was, however, accepted by Black, and its principles taught by him in Edinburgh; and before the end of the century it had practically supplanted phlogistonism in this country. Some of those who, like Kirwan, had energetically opposed the new theory ended by enthusiastically embracing it. Its introduction into Germany was mainly due to the influence of Klaproth."