"The first advance... was made by A. Einstein, who... pointed out that the... quanta of energy associated with the quantum of action seemed capable of explaining... a series of remarkable properties of light action discovered experimentally, such as Stokes's rule, the emission of electrons, and the ionization of gases, and on the other hand, by the identification of the expression for the energy of a system of resonators with the energy of a solid body, derived a formula for the specific heat of solid bodies which on the whole represented it correctly as a function of temperature, more especially exhibiting its decrease with falling temperature."
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Ref: Stoke's rule for photoluminescence: frequency of emitted light is less than or equal to the frequency absorbed for phosphorescence or fluorescence.
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The Origin and Development of the Quantum Theory
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