"Before we can rightly understand the principles of spectroscopic astronomy, we must go back to the life and work of its founder—Joseph von Fraunhofer. ...Allowing light from the Sun to pass through a prism attached to the telescope, he was amazed to find several dark lines in the spectrum. ...Fraunhofer named the more prominent lines by the letters of the alphabet from A in the red to H in the violet. They are now known as the Fraunhofer lines. ...He expressed the belief that the pair of lines in the solar spectrum which he marked D, coincided with the pair of bright lines emitted by incandescent sodium. Although he doubtless suspected that the lines conveyed intelligence regarding the elements in the Sun, he never was able properly to decipher their meaning. ...Had he lived he would probably have made the great discovery."
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Hector Macpherson, A Century's Progress in Astronomy (1906) p. 47-50.
https://en.wikiquote.org/wiki/Sodium
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Sodium
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