"... the magnificent structure of Gibbsian statistical mechanics [cannot] be viewed as founded upon ideal classical gases, Boltzmannian kinetic theory, and the virial and cluster expansions for dilute fluids! True, this last route was still frequently retravelled in textbooks more than 50 years after Gibbs’ major works were published; but it deeply misrepresents the power and range of statistical mechanics... asking ‘‘What does statistical mechanics convey to a physicist?’’ and replying: ‘‘It means that one can compute the second-virial coefficient to correct the ideal gas laws!’’ Of course, historically, that is not a totally irrelevant remark; but it is extremely misleading and, in effect, insults one of America’s greatest theoretical physicists, Josiah Willard Gibbs."
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Mathematicians from the United StatesPeople from New HavenPhysicists from the United StatesYale University alumniChemists from the United States
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Josiah Willard Gibbs
Josiah Willard Gibbs (February 11 1839 – April 28 1903) was an American theoretical physicist, chemist and mathematician. One of the greatest American scientists of all time, he devised much of the theoretical foundation for chemical thermodynamics, as well as physical chemistry and statistical mechanics.
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