"One could... safely declare that 'Physics... can be defined as that subject which treats of the transformation of energy.' The philosophical version of Herakleitos and Empedokles... a continual cycle of changes and exchanges, had... crystallized into a quantitative physical theory. But this... picture... was... incomplete. For... there was a second, equally general and fundamental element in Nature—a directional one. This had first been formulated in the 1820s by the Mozart of modern physics, Sadi Carnot. ...Carnot started with the question: What proportion of the in any system is 'available' as a means of producing ? ...Carnot demonstrated ...a one-hundred-per-cent-efficient engine could exploit only a fraction of the heat supplied to it... A 'super-efficient' machine which could exploit all the heat supplied, would be (as Carnot's mathematics proved) a machine... one could get out of it more energy than was supplied... In an ... physical changes could at most be perfectly reversible; [but] in normal cases they would result in the progressive... 'degradation' of mechanical energy by the production of unavailable heat. To characterize this... Clausius coined the word ... [T]he directional principle of Carnot and Clausias (which gave precise expression to Newton's insight that 'motion is more easily lost than got, and is continually upon the decrease') became the Second Law of Thermodynamics."
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, , The Architecture of Matter (1962)
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Entropy (thermodynamics)
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