"Enamine catalysis often delivers valuable chiral compounds such as alcohols, amines, aldehydes, and ketones. Many of these are normally not accessible using established reactions based on transition metal catalysts or on preformed enolates or enamines, illustrating the complimentary nature of organocatalysis and metallocatalysis."
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S.C. Pan, B. List, "New Concepts for Organocatalysis" in Organocatalysis (2008) edited by M.T. Reetz, B. List, S. Jaroch, H. Weinmann.
https://en.wikiquote.org/wiki/Organocatalysis
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Organocatalysis
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