Chemistry

"The word sulfur... goes... back to... the Hindu civilization... over 5,000 years ago. They had a word for sulfur... in... Sanskrit... sulvere... the enemy of copper. ...[T]hat is the ...destruction of the copper by the hot sulfur vapors... [T]he copper turns into... ...a black crumbly solid. ...The Latin [derived from sulvere] ...becomes sulphur."

"[S]ulfur beautifully burning in a gas jar full of oxygen... is a blue flame... [W]e now have a jar full of sulfurous fumes... [W]e allow the water to mix... The water has been colored green with a... ... As if by magic, the water... [turns] red and now it's gone yellow. ...[T]he ...gas ...when it reacts with water ...makes ."

"[T]he fact that sulfur has a low melting point of 115°C... has been exploited in making molds..."

"We have wonderful uses of on an everyday basis. ...[J]ust about every ...motorcar [which runs on diesel or on petrol] ...has sulfuric acid ...inside the car battery."

"[I]t comes out of... volcanoes. ...[I]n ...human history things ...from underground have had... evil connotations... During the rise of various religions and... cultures sulfur was associated with evil... especially... in Christianity... connotations of hell, damnation... the dark underworld... punishment for... sins. ...[C]onnatations which we today ...know are not true..."

"There are several ways of performing Tas'id, (a rising up) in the (the sublimatory apparatus), and the substances which the chemists sublime in it are Mercury, Arsenic sulfide, Sulfur and Sal-Amoniac. They are placed after treatment in the aludel, and the cover being fitted in position over it, a fire is lit. Then the substance rises up, and settles on the shelf..."

"If you prudently desire to make our elixir, you must extract it from a mineral root. For as Geber saith, you must obtain the perfection of the matter from the seeds thereof. Sulphur and mercury are the mineral roots, and natural principles, upon which nature herself acts and works in the mines and caverns of the earth, which are viscous water, and subtil spirits running through the pores, veins, and bowels of the mountains. Of them is produced a vapour or cloud, which is the substance and body of metals united, ascending, and reverberating upon its own proper earth, (as Geber sheweth) even till by a temperate digestion through the space of a thousand years, the matter is fixed, and converted into a mineral stone, of which metals are made."

"There are many other sulfides, but this one is... special... Known in the ancient world as dragon's blood, and the reason... this red color. ...[W]hen they heated this strongly ...(This was particularly well known in ancient China and... in southern Spain.) ...it makes two... remarkable substances. One of them is sulfur... the other... is the liquid metal... mercury. ...[T]his fired up the imagination of ...ancient philosophers ...asking questions about ultimately what are all s made of."

"I am holding... one of the most extraordinary substances known to the human race... sulfur... known... since the dawn of humanity. ...[I]t was found in volcanic regions ...and one of the most remarkable things they found about this yellow solid ...is that it burns."

"It's burning with a blue flame... giving off the most foul and acrid fumes... So there is our "burning stone," which in old English was called brimstone."

"[the gas produced by burning sulfur]... has been used as a bleach and a fumigant since ancient Egyptian times."

"[A]bout 1,200 years ago... Al Razi... started making ... and... introduced marzipan into Europe... the tradition of using... sulfur for [marzipan] molds..."

"There is another type of exploding supernova that also seeds the Galaxy with elements. This is the . This explosion involves a binary system in which a star and an intermediate-mass star (a ) orbit each other. The two stars are so close to each other that the white dwarf gradually pulls a considerable amount of material from the outer envelope of the expanding red giant. At a certain point the white dwarf will acquire so much mass that it collapses under its own weight and produces an explosion that blasts the bulk of its material into the interstellar medium—mostly in the form of iron, but also some sulfur, and . Such explosions contributed about 70 percent of the iron we see today in the Galaxy."

"From this theoretical structure of nature evolved the assumptions upon which alchemy was based: the unity of the universe and relatedness of all natural phenomena as expressed by the idea of from which all bodies were formed and into which they might again be dissolved, and the existence of a potent transmuting agent capable of promoting the change of one kind of material into another... This transmuting agent became known as the philosopher's stone, an object so quintessential it could not only transmute metals, but cure illness and prolong life....The process was composed of three stages. In the first, the alchemist heated the primary material, usually a blend of salt, mercury and sulfur, until it dissolved and turned black with decay. Under this continuous heat the liquid became dry, powdery and white. If all was done properly, the materials would eventually recombine and become a brilliant red, the color of the philosopher's stone."

"Proposals for chemical weapons that arose during the American Civil War are described. Most incendiary and all biological agents are excluded. The described proposals appeared primarily in periodicals or letters to government officials on both sides. The weapons were usually meant to temporarily disable enemy combatants, but some might have been lethal, and Civil War caregivers were ill-prepared to deal with the weapons’ effects. Evidently, none of the proposed weapons were used. In only one instance was use against civilians mentioned. Among the agents most commonly proposed were cayenne pepper or other plant-based irritants such as black pepper, snuff, mustard, and veratria. Other suggested agents included chloroform, chlorine, hydrogen cyanide, arsenic compounds, sulfur, and acids. Proponents usually suggested that the chemicals be included in explosive artillery projectiles. Less commonly proposed vehicles of delivery included fire engines, kites, and manned balloons. Some of the proposed weapons have modern counterparts."

"'isn't it brimstone morning?' 'I forgot, my dear,' rejoined Squeers; 'yes, it certainly is. We purify the boys' bloods now and then, Nickleby.' 'Purify fiddlesticks' ends,' said his lady. 'Don't think, young man, that we go to the expense of flower of brimstone and molasses, just to purify them; because if you think we carry on the business in that way, you'll find yourself mistaken, and so I tell you plainly. ...They have the brimstone and treacle, partly because if they hadn't something or other in the way of medicine they'd be always ailing and giving a world of trouble, and partly because it spoils their appetites and comes cheaper than breakfast and dinner. So, it does them good and us good at the same time, and that's fair enough I'm sure.'"

"Paracelsus' greatest triumph was the use of mercury to treat , the new disease of the day. ...Paracelsus may have heard of the treatment in his travels... or the discovery may have been serendipitous, based on... the extension of the mercury-sulfur theory of the Islamic alchemists to a tria prima... of mercury (soul), sulfur (spirit), and salt (body). But... there is no record of the number of people he adversely affected while experimenting with potions that were not effective, which may have been considerable."

"He can perform a thousand things, and is the heart of all. He can perfect metals and minerals, impart understanding to animals, produce flowers in herbs and trees, corrupt and perfect air; in short, he produces all the odours and paints all the colors of the world. ...Know friend, that sulphur is the virtue of the world. And though Nature's second-born, yet the oldest of all things. To those who know him, however, he is as obedient as a little child. He is most easily recognized by the vital spirit in animals, the colour in metals, the odour in plants. Without his help his mother can do nothing."

"In some parts of the East, sulphur is separated from the earthy matter wherewith it is mixed in the soil, by heating the crude material very strongly in earthen pots, each covered with another similar pot inverted on it. The sulphur melts and then becomes gaseous and the gaseous, sulphur condenses in the upper pots, which are comparatively cool; the fine yellow powder which condenses is approximately pure sulphur; the earthy impurities remain in the lower pots."

"The crude sulphur found in Sicily and other places is heated in pots, whereupon the sulphur melts and floats on the surface of the earthy matter which remains at the bottoms of the pots; the melted sulphur is poured into moulds, where it solidifies, and the earthy matter left in the pots is thrown away."

"Pliny recorded processes involving metals, salts, sulfur, glass, mortar, soot, ash, and a large variety of s, earths, and stones."

"Now, according to the ancient Sages there are two principles of things, and more particularly of metals, namely, Sulphur and Mercury; according to the Moderns there are three: Salt, Sulphur, and Mercury, and the source of these principles are the elements; of which it therefore behoves us to speak first. Be it known to the students of this art that there are four elements, and that each has at its centre another element which makes it what it is. These are the four pillars of the world. They were in the beginning evolved and moulded out of chaos by the hand of the Creator; and it is their contrary action which keeps up the harmony and equilibrium of the mundane machinery; it is they which, through the virtue of celestial influences, produce all things above and beneath the earth."

"There are seven things that can be elongated by hammering at the furnace, namely Sol, that is gold, luna (silver), tin, copper (aes), iron, lead. These are formed in nature under the earth. Gold is generated in the earth by the great heat of the sun from excellent quicksilver and red and pure sulphur by digestion in the rocks for a hundred years or more; silver from pure quicksilver and pure sulphur digested for a hundred years. But copper (...cuprum instead of aes) from impure quicksilver and impure sulphur digested for a hundred years. ...Lead, the philosophers say, is made under the earth from impure and thick quicksilver and from the worst sulphur and is a crude mixture and not well digested. And lead... renders gold breakable... Tin, however, is made from excellent and pure quicksilver, but from the poorest sulphur impure and not well digested. Iron is from thick quicksilver and thick red sulphur, and is not sufficiently digested."

"Mineral bodies are vapors which have coagulated in nature in the course of long lapses of time, and the first things which coagulate are quicksilver and sulphur, for these and not water or oil (oleum) are the elements of minerals, for the first... (quicksilver) is generated from a water and the other (sulphur) from an oil. Upon these things there operates a gentle digestion constantly with heat and moisture until they are solidified and from them (metallic) bodies are generated by gradual mutation in thousands of years. For if they remain in their minerals, nature purifies them until they arrive at a kind of gold or silver. But by the subtlety of the artist, transmutation of this kind is made in one day or in a brief space of time."

"The did not arrive in China until around 1500 BCE, and iron appeared only about 500 BCE, but by the beginning of their alchemical age, around 100 CE, the Chinese had knowledge of and ... mercury, sulfur and several of the common salts, such as ."

"[C]hemical weapons were not new to the world. Besieged towns had thrown pots of burning sulfur, asphalt and pitch on soldiers since at least 200 CE."

"Reminiscent of Aristotle, Jabir proposed... two exhalations: "earthy smoke" (small particles of earth on their way to becoming fire) and "watery vapor" (small particles of water on their way to becoming air). These, he believed, mingled to become the metals. But Jabir modified the Aristotelian approach by proposing that exhalations underwent intermediate transformations into sulfur and mercury before becoming metal. The reason for the existence of different types of metals, he believed, was that the sulfur and mercury were not always pure. He proposed that if the right proportions of sulfur and mercury with the right purity could be found... gold would result."

"By 3000 BCE the Sumerians, perhaps while heating copper to make it more malleable, had discovered that more copper could be retrieved from the fire if the metal were heated with certain types of dirt and stones—that is, certain earths. These earths were the metal s, and the process they discovered, ', reduced metal salts to pure metal by the action of in the fire. The process of changing metal salts into pure metal is known as reduction because the metal without the accompanying oxygen, , or sulfur of the salt weighs less than the ore. Eventually metal workers learned to distinguish various metal-bearing ores by color, texture, weight, flame color, or smell when heated (such as garlic odor of ores) and they could produce a desired material on demand."

"[O]ne of the things that's associated with sulfur and... its compounds is unpleasant smells."

"I'm going to melt the sulfur. ...The ...sulfur has molecules whose formulae are S8 ...They're pocket rings. They're like little crowns. ...[W]hen you get to roughly 160°C ...they break up ...and they start making a . They polymerize, like a plastic. ...I'm going to pour it into some cold water. ...like golden syrup. ...It's what we call plastic sulfur. ...[I]t's neither a liquid nor a solid."

"Sulphuric acid he made by distilling green vitriol (ferrous sulphate), and by distilling nitre (potassium nitrate), and (double sulphate of potassium and aluminium). he prepared, but said it was of little use as a medicine."

"His alchemical doctrine, that everything consisted of three elements—mercury, sulphur, and salt—is adapted from old authors, but he was the first to use the word "alcahest" to indicate the universal menstruum or , which at that time was a special object of research. He describes this liquor, alcahest, as having great power over the , comforting and confirming it, and preserving it from dropsy and other diseases that take their origin within it. ...Unhappily, he does not give precise directions for the preparation of this invaluable remedy."

"Paracelsus had discarded the disgusting decoctions of Galen and introduced chemical medicines, while Libavius and Sala had dismissed the fanatical conceptions which disfigured and almost nullified the teachings of both Paracelsians and Rosicrucians, but chemists still adhered either to the Aristotelian doctrine of the four elements, or to the later theory of the three principles (mercury, sulphur, and salt). (1577—1644) was the first to deny these propositions, and to begin a revolution in the philosophy of chemistry."

"In 1648 he demonstrated the possibility of making blue vitriol () by boiling copper with sulphuric acid."

"He strongly maintained the virtues of aurum potabile (liquid gold), and wrote a book entitled Medicinae Chymicae et Veri Potabilis Auri Assertio (1610). Another tract, De Lapide philosophorum et Lapide Rebis, related to the older alchemy. ...[I]n alchemical symbolism "Rebis" was the name given to the hermaphrodite figure representing the union of the great philosophical principles, sulphur and mercury, in the operation of making the philosopher's stone..."

"He asserted that the metals are composed of the mercury and sulphur of the philosophers, to which he added philosophical salt. The philosopher's stone, he said, is composed of the same materials."

"He observed that the fumes of sulphur blacken ; he purified by means of arsenic and ; he made artificial rubies and other precious stones by tinting glass with metallic oxides; he described fluor spar as a flux for metals and their oxides; he oxidised sulphur with ; he knew that alcohol is obtained by distilling the fermented juice of sweet fruits; he proved that the acid extracted from and from ferrous sulphate (green vitriol) is the same as that obtained by burning sulphur with saltpetre, that is to say, it is sulphuric acid; and he discovered tin tetrachloride (stannic chloride), which is sometimes called Liquor fumans Libavii. It is a truly remarkable record of practical work, considering the age in which Libavius lived."

"[T]he most valuable work of Cavendish was contained in the two papers "Experiments on Air" (1784-5)... to determine the phlogistication of air... [i.e.,] the change in air when s are calcined in contact with it, and when sulphur, , or similar substances, are burned in it."

"[A]lchemists accounted for the diversity of metals by five causes:— 1. Variation in the proportion of the principles, mercury and sulphur. 2. Variation in the purity of these principles. 3. Variation in the duration of the period of concoction to which the compound was subjected in the bowels of the earth. 4. Variation in planetary influences. 5. Variation in accidental influences."

"The sulphur, the property of dryness and heat, ultimately overcame the mercury, the property of wetness and cold, and thus changes were effected. ...[S]ulphur was the father, mercury the mother, and metals were conceived between them. In this expression the philosophical principles are meant, not the ordinary substances called sulphur and mercury."

"At a still later date it was argued that exact and natural sciences proceed by induction and deduction, and occult and spiritual sciences by analogy. Following out this line of thought the alchemists produced the following remarkable :—"

"Volcanic ash, despite the name, is dense as rock and can cause significant damage to structures, power lines and communications. It is also toxic because it contains chemicals such as sulfur, chlorine or fluorine, and it can therefore affect water supplies."

"The mercury of a metal... represented its lustre, volatility, fusibility, and malleability; the sulphur of the metal, its colour, combustibility, affinity, and hardness."

"These mystic alchemists interpreted the three principles in their own fashion. Mercury, the passive and female principle, was matter; sulphur, the active and male principle, was force; and salt, the middle term in the proposition, was movement, which applied force to matter. Or, expressed in another shape, mercury was the subject: sulphur, the cause; and salt, the effect. Symbolically, the theory was represented by an equilateral triangle, in one angle of which was the sign of sulphur or force; in the second, the sign of mercury or matter; and in the third, the sign of salt or movement."

"He noticed that when copper and sulphur are mixed, they exhibit an , which increases with increasing temperature until finally they combine, and all traces of electricity disappear. Hence, he inferred that the same forces which, acting on masses at a distance, produce electric phenomena, when acting on atoms at small distances, produce chemical combination, the positive electricity of the one atom attracting and holding the negative of the other. In the positive charge is on one and the negative on the other, but these two charges have to be discharged through the electrode before the elements are set free. This is the reverse of what takes place in combination. Davy in this view differed from the electro-chemical theory of Berzelius."

"This is a volcano... that cloud of smoke... is... full of sulfurous fumes..."

"Mifepristone may be the least marketed pharmaceutical product in the U.S. There aren’t any ads for it on TV. Most doctors can’t prescribe it. Pharmacists don’t know much about it, since it doesn’t sit on the shelves at CVS or Walgreens. It would be reasonable to assume this is all because mifepristone is exceptionally dangerous. But it sends fewer people to the ER than Tylenol or Viagra."

"The idea of a Kinetic Theory of Gases originated with J. Bernouilli about the middle of the last century, but the first establishment of the theory on a scientific basis is due to Professor Clausius. During the last few years the theory has been greatly developed by many physicists, especially by Professor Clerk Maxwell in England and Professor Clausius and Dr. Ludwig Boltzmann... and although still beset by formidable difficulties, it has succeeded in explaining most of the established laws of gases in so remarkable a manner as to render it well worthy of the attentive consideration of scientific men. ...For the most part I have followed the method of treatment adopted by Dr. Ludwig Boltzmann in some very interesting memoirs ..."

"The old mechanical and atomic hypotheses have, during recent years, become so plausible that they have ceased to seem like hypotheses; atoms are no longer just a convenient fiction. It seems almost as if we could see them, now that we know how to count them. ...The kinetic theory of gases has thus received unexpected corroboration. ...The remarkable counting of the number of atoms by Perrin completed the triumph of the atomic theory. ...In the processes used with the Brownian phenomenon, or in those used for the law of radiation, we do not deal directly with the number of atoms, but with their degrees of freedom of movement. In that process where we consider the blue of the sky, the mechanical properties of the atoms come into play; the atoms are looked upon as producing an optical discontinuity. ...The atom of the chemist is now a reality. But that does not mean that we have reached the ultimate limit of the divisibility of matter. When Democritus invented the atom he considered it as the absolutely indivisible element within which there would be nothing further to distinguish. That is what the word meant in Greek. ... the atom of the chemist would not have satisfied him since that is not indivisible; it is not a true element; it is not free from mystery, from secrets. The chemist's atom is a universe. Democritus would have considered, even after so much trouble in finding it, that we were still only at the beginning of our search—these philosophers are never satisfied. ...This atom disintegrates into yet smaller atoms. What we call is the perpetual breaking up of atoms. ...Each atom is like a sort of solar system where the small negative electrons play the role of planets revolving around the great... sun. ...the atom of a radioactive body is a universe within itself and a world subject to chance."

"The researches of Galileo, followed up by Huygens and others, led to those modern conceptions of Force and Law, which have revolutionized the intellectual world. The great attention given to mechanics in the seventeenth century soon so emphasized these conceptions as to give rise to the Mechanical Philosophy, a doctrine that all the phenomena of the physical universe are to be explained upon mechanical principles. Newton's great discovery imparted a new impetus to this tendency. The old notion that heat consists in an agitation of corpuscles was now applied as an explanation to the chief properties of gases. The first suggestion in this direction was that the pressure of gases is explained by the battering of the particles against the walls of the containing vessel, which explained Boyle's law of the compressibility of air. Later, the expansion of gases, Avogadro's chemical law, the diffusion and viscosity of gases, and the action of Crooke's radiometer were shown to be consequences of the same kinetical theory; but other phenomena, such as the ratio of the specific heat at constant volume to that at constant pressure, require additional hypotheses, which we have little reason to suppose are simple, so that we find ourselves quite afloat. In like manner with regard to light..."