Sulfur

"Reminiscent of Aristotle, Jabir proposed... two exhalations: "earthy smoke" (small particles of earth on their way to becoming fire) and "watery vapor" (small particles of water on their way to becoming air). These, he believed, mingled to become the metals. But Jabir modified the Aristotelian approach by proposing that exhalations underwent intermediate transformations into sulfur and mercury before becoming metal. The reason for the existence of different types of metals, he believed, was that the sulfur and mercury were not always pure. He proposed that if the right proportions of sulfur and mercury with the right purity could be found... gold would result."

"Paracelsus' greatest triumph was the use of mercury to treat , the new disease of the day. ...Paracelsus may have heard of the treatment in his travels... or the discovery may have been serendipitous, based on... the extension of the mercury-sulfur theory of the Islamic alchemists to a tria prima... of mercury (soul), sulfur (spirit), and salt (body). But... there is no record of the number of people he adversely affected while experimenting with potions that were not effective, which may have been considerable."

"I am holding... one of the most extraordinary substances known to the human race... sulfur... known... since the dawn of humanity. ...[I]t was found in volcanic regions ...and one of the most remarkable things they found about this yellow solid ...is that it burns."

"It's burning with a blue flame... giving off the most foul and acrid fumes... So there is our "burning stone," which in old English was called brimstone."

"[O]ne of the things that's associated with sulfur and... its compounds is unpleasant smells."

"This is a volcano... that cloud of smoke... is... full of sulfurous fumes..."

"The word sulfur... goes... back to... the Hindu civilization... over 5,000 years ago. They had a word for sulfur... in... Sanskrit... sulvere... the enemy of copper. ...[T]hat is the ...destruction of the copper by the hot sulfur vapors... [T]he copper turns into... ...a black crumbly solid. ...The Latin [derived from sulvere] ...becomes sulphur."

"[S]ulfur beautifully burning in a gas jar full of oxygen... is a blue flame... [W]e now have a jar full of sulfurous fumes... [W]e allow the water to mix... The water has been colored green with a... ... As if by magic, the water... [turns] red and now it's gone yellow. ...[T]he ...gas ...when it reacts with water ...makes ."

"[I]t comes out of... volcanoes. ...[I]n ...human history things ...from underground have had... evil connotations... During the rise of various religions and... cultures sulfur was associated with evil... especially... in Christianity... connotations of hell, damnation... the dark underworld... punishment for... sins. ...[C]onnatations which we today ...know are not true..."

"[W]hen you heat fool's gold... some crushed s... [y]ou can see the appearance of this yellow color, and ...a little bit of crackling... . ...[T]he crystals... are breaking up into a powder ...because when you heat things up, they expand on the outside, but not on the inside. ...The yellow stuff is beginning to collect ...It is sulfur ..."

"[P]yrites is the most widely distributed mineral of sulfur ...the chemical name is iron sulfide. ...It has the formula FeS2 and ...thousands of years ago people ...recognized that when you heat it, you ...make sulfur ..."

"This mineral ...is .... It's lead sulfide. ...Beautiful silver crystals. If you heat this strongly, this too will make sulfur come off."

"There are many other sulfides, but this one is... special... Known in the ancient world as dragon's blood, and the reason... this red color. ...[W]hen they heated this strongly ...(This was particularly well known in ancient China and... in southern Spain.) ...it makes two... remarkable substances. One of them is sulfur... the other... is the liquid metal... mercury. ...[T]his fired up the imagination of ...ancient philosophers ...asking questions about ultimately what are all s made of."

"[T]he great Arabic alchemists... in the 8th or 9th century AD... came up with the idea that ultimately all metals are composed of sulfur and mercury..."

"[T]he sulfur-mercury theory... reasoning was... straightforward. They said... "If you mix this [mercury] with this [sulfur] in the right proportion, you can make any metal.""

"Science is very difficult, and... the ancient world... was... a world of correspondences. ...[S]omething ...could well be ...actually made of things that make it look like something. ...That was the cleverest way ...people used to view the world in those days."

"This sulfur-mercury theory... people continued to believe... for a thousand years."

"I have some beautiful crystals... these green ones and the blue ones... have been observed... [from] water evaporating on the side of lakes... close to volcanoes... [T]hey have... a glassy appearance. ...[T]he Sumerians, 2000 years ago ...described these ...The Latin word for glass is vitriolus [or vitrum] and so glassy substance became known as vitriols. ...[T]he medieval chemists discovered that if you heat these [crystals] very strongly... they give off a... terribly powerful smell and... a liquid which is capable of dissolving... metals. ...It was called oil of vitriol because it came from those glassy substances, but today we call it ."

"[T]he types of substances... made when metals dissolve in [sulfuric] acids...are called s. In the olden language they were called s. ...Here I have some beautiful crystals of copper sulfate ...blue vitriol. ...Here... iron sulfate... iron [or green] vitriol, which is the first sulfate... that they made the... sulfuric acid from, and... some crystals of white vitriol... . ...But I want to show you a most interesting [clear] mineral ...extremely beautiful. ...This comes out of the ground ...[A]lmost everyone ...would have lots of this in your houses. ...The mineral is called . The chemical name is ...[from which] we make plaster. ...Once again sulfur playing a key role in our everyday lives."

"We have wonderful uses of on an everyday basis. ...[J]ust about every ...motorcar [which runs on diesel or on petrol] ...has sulfuric acid ...inside the car battery."

"[T]he fact that sulfur has a low melting point of 115°C... has been exploited in making molds..."

"I'm going to melt the sulfur. ...The ...sulfur has molecules whose formulae are S8 ...They're pocket rings. They're like little crowns. ...[W]hen you get to roughly 160°C ...they break up ...and they start making a . They polymerize, like a plastic. ...I'm going to pour it into some cold water. ...like golden syrup. ...It's what we call plastic sulfur. ...[I]t's neither a liquid nor a solid."

"[the gas produced by burning sulfur]... has been used as a bleach and a fumigant since ancient Egyptian times."

"[A]bout 1,200 years ago... Al Razi... started making ... and... introduced marzipan into Europe... the tradition of using... sulfur for [marzipan] molds..."

"[A]n electric machine... first produced by ... is based on... attractor forces. ...[I]f you take a lump of sulfur and... rub it with a silk cloth... it will start to pick up bits of paper... hair... feather... [A]nother mineral... [Latin electrum]... had the same property. ...Otto von Guericke made a special globe out of sulfur ...and he described the remarkable reactions of things being ...attracted to it ...[I]t was the birth of ..."

"[T]he reason why is so interesting and why... the chemistry of sulfur is so interesting, is because sulfur is a very, very reactive element. Not only is it reactive, but it can form many different kinds of chemical combination..."

"The way we test... for... is to put in a burning splint... and you see it has gone out."

"This gas comes out of volcanoes as well as sulfur dioxide, and... is called . ...It has a phenomenally unpleasant smell of rotten eggs. Apart from that, it's unbelievably poisonous. ...[I]t undergoes an extraordinarily interesting reaction with sulfur dioxide. ...The lower jar is going yellow ...[W]e have made sulfur. ...also ...water. ...Two gases have reacted together to make a solid and a liquid. Secondly, two compounds of sulfur have made the element sulfur... Furthermore... it's... a redox reaction in which sulfur is reduced in one... and oxidized in the other. ...[M]any geologists believe that these two gases come out of volcanoes together and... make huge deposits of sulfur... found at the mouths of volcanoes."

"Sulfur is today obtained mainly from extraction from fossil fuels, from , from gas and from crude oil."

"This is a jar full of sulfur dioxide. ...[W]hen we pour solution, which is purple. ...It's lost its color. Let's try... [yellow] solution... Magic [as it turns ]? No, it's chemistry... [T]he sulfur dioxide is acting as a . It has caused them to change color on account of the change in of from +7 to +2, from +6 to +3."

"[T]here's burning, and... we lower it into sulfur dioxide. It carried on burning for a little while... [I]n sulfur dioxide, magnesium... breaks the bonds between the sulfur and the oxygen... itself becoming ... and releasing a little... sulfur... [T]hat's an example of sulfur dioxide as an ."

"Sulfur dioxide... is... present in many wines. ...Usually ...sulfur dioxide is used as a food preservative, ...but they usually call it ...SO3^2-."

"[S]ulfur is unbelievably reactive. ...Sulfur can form 4 hooks, 2 hooks, -2. s +4, +6 and -2, 0 in... the element..."

"is adding tiny amounts of sulfur to rubber to make it much stiffer. ...If not for ...vulcanization, we'd have no tires ...on motorcars, on airplanes or bicycles. We'd have no hoses in cars and so on... The world would be quite different. Vulcanization was invented by in 1840, one of the most important uses of sulfur today."

"These are the three ingredients in , which were known to the Chinese ...about 1,000 years ago: sulfur, and potassium nitrate. ...[T]hey're used in explosives and fireworks..."