"But as I was... too much devoted to pure phenomenology to inquire more closely into the relation between entropy and probability, I felt compelled to limit myself to the available experimental results. Now, at that time... 1899, interest was centred on the law of the distribution of energy... proposed by W. Wien... On calculating the relation following from this law between the entropy and energy of a resonator the remarkable result is obtained that the reciprocal value of the above differential coeffcient... R, is proportional to the energy. This extremely simple relation can be regarded as an adequate expression of Wien's law..."
January 1, 1970
https://en.wikiquote.org/wiki/Entropy_(thermodynamics)