"Boltzmann decided to publish his lectures, in which the most important parts of the theory, including his ...contributions, were carefully explained. ...[H]e included his mature reflections and speculations on such questions as the nature of irreversibility and the justification for using statistical methods in physics. His Vorlesungen über Gastheorie was... the standard reference... for advanced researchers, ...[and] a popular textbook ...for the first quarter of the [20th] century ...The reason why the classical theory works is that, while the internal structure of molecules must be described by quantum mechanics, the interaction between two molecules can be fairly well described by a classical model which ignores this structure and simply uses a postulated force law whose parameters can be chosen to fit experimental data. ...Aside from phenomena at very high densities or very low temperatures, the only property that the classical theory fails to account for is the ratio of specific heats. ...Boltzmann ...simply concludes that for some unknown reason all the possible internal motions of a molecule do not have an equal share in the total energy, and takes this into account as an empirical fact."