"Atmospheric concentrations of CFCs rose steadily following their first synthesis in 1928 and peaked in the early 1990s. Many other industrially useful fluorinated compounds... have very long atmospheric lifetimes, which is of concern... s (HFCs), which are replacing CFCs, have a greenhouse effect, but it is much less pronounced..."
January 1, 1970
https://en.wikiquote.org/wiki/Scientific_consensus_on_climate_change