"Carboxylic acids react with alcohols to form esters, as long as a mineral acid catalyst is present. This reaction is only slightly exothermic, and its equilibrium may be shifted in either direction by the choice of reaction conditions. The reverse of ester formation is ester hydrolysis. The mechanism of esterifi cation is acid-catalyzed addition of alcohol to the carbonyl group followed by acid-catalyzed dehydration. Intramolecular ester formation results in lactones, favored only when five- or six-membered rings are produced."
January 1, 1970