"What made silica so interesting was that... it did not seem to follow the established rules of chemical combination. In Smithson's time, chemical combination was... an acid combining with an alkali to produce a stable, neutral... "." Acids did not combine chemically with each other, nor did alkalis... [A] substance... found to contain an alkali... must also contain an acid—and vice versa. Bergman's description of the compounds containing earths as... "natural compositions of acids" meant... the other component must be alkaline—which the earths all seemed to be, except for silica."
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Sources
Steven Turner, The Science of James Smithson: Discoveries from the Smithsonian Founder (2020) p. 96.
https://en.wikiquote.org/wiki/Earth_(historical_chemistry)
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Earth (historical chemistry)
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