"Carnot's Principle. ...If physical phenomena were due exclusively to the movements of atoms whose mutual attraction depended only on the distance, it seems that all these phenomena should be reversible; if all the initial velocities were reversed, these atoms, always subjected to the same forces, ought to go over their trajectories in the contrary sense, just as the earth would describe in the retrograde sense this same elliptic orbit which it describes in the direct sense, if the initial conditions of its motion had been reversed. On this account, if a physical phenomenon is possible, the inverse phenomenon should be equally so, and one should be able to reascend the course of time. Now, it is not so in nature, and this is precisely what the principle of Carnot teaches us; heat can pass from the warm body to the cold body; it is impossible afterward to make it take the inverse route and to reestablish differences of temperature which have been effaced. Motion can be wholly dissipated and transformed into heat by friction; the contrary transformation can never be made except partially. We have striven to reconcile this apparent contradiction. If the world tends toward uniformity, this is not because its ultimate parts, at first unlike, tend to become less and less different; it is because, shifting at random, they end by blending. For an eye which should distinguish all the elements, the variety would remain always as great; each grain of this dust preserves its originality and does not model itself on its neighbors; but as the blend becomes more and more intimate, our gross senses perceive only the uniformity. This is why for example, temperatures tend to a level, without the possibility of going backwards. A drop of wine falls into a glass of water; whatever may be the law of the internal motion of the liquid, we shall soon see it colored of a uniform rosy tint, and however much from this moment one may shake it afterwards, the wine and the water do not seem capable of again separating. Here we have the type of the irreversible physical phenomenon : to hide a grain of barley in a heap of wheat, this is easy; afterwards to find it again and get it out, this is practically impossible. All this Maxwell and Boltzmann have explained; but the one who has seen it most clearly, in a book too little read because it is a little difficult to read, is Gibbs, in his 'Elementary Principles of Statistical Mechanics.’"
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Henri Poincaré, ' (1913, Reprinted 1921) Tr. of La Science et l'Hypothèse (1902) Ch. VII The Present Crisis of Mathematical Physics, pp. 303-304.
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Statistical mechanics
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